“…Changes in the lineshape and peak positions of the XPS C1s peaks can be observed as the substrate temperature is increased. Moreover, the C1s peak position shifts toward lower binding energies, the peak width is narrowed, and its shape becomes asymmetric, indicating the transformation of sp 3 sites into sp 2 sites with the increase of substrate temperature [40]. Fig.…”
“…Changes in the lineshape and peak positions of the XPS C1s peaks can be observed as the substrate temperature is increased. Moreover, the C1s peak position shifts toward lower binding energies, the peak width is narrowed, and its shape becomes asymmetric, indicating the transformation of sp 3 sites into sp 2 sites with the increase of substrate temperature [40]. Fig.…”
“…We introduced a mask with a 10-mm square hole between the target and substrate. In this experiment, carbon film was previously deposited on substrate by PLD in oxygen plasma ambience as reported in [5], and then boron was deposited over the carbon film in vacuum for 5 − 240 min. All the experiments were carried out at room temperature.…”
Section: Experimental Setup and Proceduresmentioning
confidence: 99%
“…Fig. 1 shows the AFM image of the film surface: (a) carbon film deposited in oxygen plasma ambience [5] and (b) the film after boron was deposited for 120 min on film (a). Nanometer-size particles (nanoparticle) were seen on film (a).…”
Section: Characterization Of Film Propertymentioning
confidence: 99%
“…The B 1s spectra of the film also contained two different components (not shown in the text), B-B bond (the peak binding energy is 188.6 eV) and B-C bond (190.6 eV) [7]. The C 1s spectra was deconvoluted into four components as similarly performed in [5];…”
Section: Analyses Of Film Property and Chemical Compositionmentioning
Double layer films of boron and carbon were prepared by pulsed laser deposition (PLD) on silicon substrates. The film surface morphology was examined by atomic force microscopy (AFM). The chemical composition of the elements, carbon, boron, silicon and oxygen, and bonding state of carbon atoms as a function of the depth from the film surface were analyzed by X-ray photoelectron spectroscopy (XPS) with argon ion sputtering technique. Carbon atoms bonded to boron (C-B) were observed as well as carbon atoms bonded to carbon (C-C).
“…In the other approaches similar to the PLD, the pulsed plasma deposition method has been broadly used for the formation of the DLC and other materials [6,11,12]. Due to the kinetic energy of the carbon particle in the high temperature plasma flow, the DLC film could be deposited on the substrate with the plasma [13][14][15]. It is possible to increase the kinetic energy of the carbon particles with the plasma torch at elevated temperatures of the plume under the pulsed laser radiation.…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.