2020
DOI: 10.1021/acs.jpclett.0c01507
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Effects of Aspect Ratio Heterogeneity of an Assembly of Gold Nanorod on Localized Surface Plasmon Resonance

Abstract: We examine the effects of aspect ratio (AR) heterogeneity of an assembly of gold nanorods (GNRs) in a colloid on the total cross-section for its light scattering via localized surface plasmons at visible wavelengths. We observe the extraordinary broadening of the extinction spectrum of light through an assembly of GNRs, a colloidal mixture of those having two different ARs. The interparticle distance estimated as ∼1.2–1.3 μm, being greater than the incident wavelength, allows the radiative dipolar coupling to … Show more

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Cited by 21 publications
(19 citation statements)
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“…LSPR is an optical phenomenon generated by light when it interacts with nanoparticles that are smaller than the incident wavelength. [38][39][40][41][42] When the frequency of the light matches the whole vibration frequency of the free carrier of the nanoparticles, the nanoparticles have a strong absorption effect on the photon energy, and a strong resonance absorption peak appears in the spectrum. The absorption of LSPR can be described by the Drude model [43] ω…”
Section: Overview Of Plasmonic Metal Oxide Ncsmentioning
confidence: 99%
“…LSPR is an optical phenomenon generated by light when it interacts with nanoparticles that are smaller than the incident wavelength. [38][39][40][41][42] When the frequency of the light matches the whole vibration frequency of the free carrier of the nanoparticles, the nanoparticles have a strong absorption effect on the photon energy, and a strong resonance absorption peak appears in the spectrum. The absorption of LSPR can be described by the Drude model [43] ω…”
Section: Overview Of Plasmonic Metal Oxide Ncsmentioning
confidence: 99%
“…The SEM image of the SiO 2 layer that has not only dye molecules but also AgNPs embedded in it shows distribution of a clustered pattern of AgNPs, as shown in Figure S2b. The fact that the inter-particle distance that varies in a certain range may affect the LSPR extinction spectrum into a broader one due to dipole-dipole interaction [40]. Using a spectrometer (USB-2000, Ocean Optics, Orlando, FL, USA), we measured the emission spectrum of the rhodamine 110 embedded in the SiO 2 layer under illumination of dye excitation light of a LED centered at 470 nm wavelength (M470L3, Thorlabs, Newton, MA, USA).…”
Section: Experimental Section 21 Fabrication Of the Plasmonic Chip Fo...mentioning
confidence: 99%
“…The oscillating plasmons would re-radiate optical energy of light in the form of elastic scattering with its cross section much larger than the physical cross section of a nanoparticle [ 88 ]. In addition, Ohmic loss occurs due to electron-electron scattering into heat.…”
Section: Localized Surface Plasmon Resonance For Detecting Crpmentioning
confidence: 99%