Effect polyethylene glycol (PEG 400) to the physical properties of gadolinium doped cerium (Ce_0.9Gd_0.1O_1.95) nanoparticles synthesized by co-precipitation method

Abstract

Cerium oxide base materials have been attracting great attention as a promising electrolyte for intermediate temperature of solid oxide fuel cell (IT-SOFC) due to its excellent conductivity at a lower temperature. In this works, cerium from Indonesia local raw material was developed as a cheaper alternative precursor for preparing gadolinium doped cerium (Ce0.9Gd0.1O1.95 or GDC10) electrolyte. The effects of polyethylene glycol 400 (PEG 400) as a surfactant on to physical properties of GDC10 electrolyte were studied. GDC10 powders were synthesized using co-precipitation method with the addition of various PEG 400 concentration i.e 0,1,2 and 3v/v%. Synthesized powders were characterized by using X-Ray Diffraction (XRD), Particle Size Analyzer (PSA), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Fourier Transform Infrared (FTIR) Spectroscopy. The XRD analysis indicates that crystallinity was enhanced and all of the peaks on samples correspond to the fluorite crystal structure of single phase CeO2. The average crystallite size is about 11.37, 7.27, 6.75 and 7.02 nm for PEG 400 concentration of 0, 1, 2 and 3v/v%, respectively. SEM images show different morphology of particle regarding with the addition of surfactant. Particle size analysis exhibits decreasing of particle diameter as the addition of PEG surfactant. The smallest particle size was about 1.47 μm for 1v/v% of PEG concentration. The results of this works confirm that the addition of PEG 400 surfactant strongly affects particle size and morphology of GDC10 powders. However, addition PEG 400 as surfactant should be delivered in a certain amount to give optimum effects where according to this works it is about 1 -2v/v%.