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Composite anodes made of NiO and SDC-(Li/Na)2CO3 were investigated in relation to their structure, morphology, and porosity. As a first step, the anode powder was prepared by mixing the NiO with SDC-(Li/Na)2CO3 via solid state reaction in weight percentage of 60 : 40 wt% and in various compositions of carbonates (20 and 30wt%), namely NiO-SDC8020 and NiO-SDC7030, respectively. The powder mixtures were then calcined at 680oC. The resultant powder was fine with surface area of about 13.10-13.70 m2/g and an average particle size of 0.32-0.37µm. The powders consist of two phases i.e. the cubic NiO and face-centered cubic structure SDC-(Li/Na)2CO3 as confirmed with x-ray diffraction. The microstructures were observed under scanning electron microscopy (SEM). The anode pellets were later compacted at different pressures (27, 32 and 37 MPa) and sintered at 600oC. The optimum porosity (20.99-24.78%) was achieved for samples of NiO-SDC8020 and NiO-SDC7030 sintered at 600oC and cold pressed at 32 and 37 MPa.

LaNi5 is widely used in various applications. Many methods to produce LaNi5 particles have been reported but information for the large-scale production, so far, is less available. This study aimed to evaluate the project for the production of LaNi5 particles using combustion-reduction (CR) and co-precipitation-reduction (CPR) methods based on engineering and economic perspective. Engineering evaluation was conducted by evaluating the CR and CPR processes from stoichiometry. For the economic evaluation, several economic parameters were calculated in the ideal condition including gross profit margin (GPM), payback period (PBP), break-even point (BEP), cumulative net present value (CNPV), profitability index (PI), internal rate return (IRR), and return on investment (ROI). For the worst cases in the project, it was done by calculating both the internal problems (i.e., raw materials, sales, utility, labor, employee, fixed cost, variable cost, and production capacity) and the external issues (i.e., taxes and subsidiaries). The engineering analysis provided the information that CR and CPR projects are prospective for being able to be done using commercial apparatuses. The economic analysis from GPM, PBP, BEP, CNPV, and PI showed the positive results, while IRR and ROI showed the negative ones, indicating that the projects are acceptable for large-scale production, but it seems to be less attractive for industrial investors. The analysis also confirmed that the CR process was more prospective than the CPR process. This work has demonstrated the important of the projects for further developments.

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Composite electrolytes made of samarium-doped cerium (SDC, Ce0.8Sm0.2O1.9) and (67 mol% Li/ 33mol% Na)2CO3 carbonate salts were investigated in relation to their structure, morphology and porosity of the electrolyte. The fabrication of the SDC–(Li/Na)2CO3 composite electrolytes were achieved in two steps: step (1) preparation of the samarium-doped cerium powders by sol-gel; step (2) mixing of the samarium-doped cerium with carbonates in various compositions by solid state reaction. The electrolyte pellets were compacted at different pressures (25 and 50 MPa) and sintered at 600oC, 700oC and 800oC. The XRD results demonstrated that the introduction of carbonates did not change the SDC phase structure. FESEM images showed that the carbonate component was amorphous and well distributed in the SDC. The lowest porosity (2.92%) was achieved for samples with carbonate content of 30% (SDC7030) sintered at 800oC and cold pressed at 50MPa.

ABSTRAKPenggunaan paduan aluminium AA 333 sebagai komponen otomotif semakin berkembang bersamaan dengan semakin berkembangnya keinginan untuk mengurangi berat dari komponen yang digunakan. Namun paduan aluminium AA 333 as-cast masih memiliki sifat mekanis yang rendah sehingga diperlukan proses lain untuk meningkatkan kekerasannya, salah satunya melalui proses perlakuan panas.

Composite cathodes made of perovskite La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) and SDC carbonates (SDC-(Li/Na)2CO3) were investigated in relation to their structure, morphology, thermal expansion coefficient and porosity. As a first step, the LSCF powder was prepared by sol-gel technique. This was followed by the preparation of the LSCF-SDC carbonates composite cathode by mixing the LSCF with SDC-(Li/Na)2CO3 electrolyte via solid state reaction in various compositions, i.e. 30, 40 and 50 wt.%, namely 70LSCF-30SDC7030, 60LSCF-40SDC7030 and 50LSCF-50SDC7030, respectively. The powder mixtures were then calcined at 680oC. The resultant powder was fine with surface area of about 3.39-7.42 m2/g and particle size of 0.56-0.66µm. The powder consists of two distinct phases, i.e. LSCF and SDC-(Li/Na)2CO3 as confirmed with x-ray diffraction. The microstructures were observed under scanning electron microscopy (SEM). Increasing the amount of the SDC-(Li/Na)2CO3 electrolyte in the composite cathode was found to bring the thermal expansion of the cathode closer to that of the electrolyte. The cathode pellets were later compacted at different pressures (27, 32 and 37 MPa) and sintered at 600oC. The optimum porosity (20.99-24.98%) was achieved for samples with SDC-(Li/Na)2CO3 content of 30-50% sintered at 600oC and cold pressed at 37 MPa.