Effect of solution treatment temperature on trigger stress for stress induced martensitic transformation (SIMT) in Ti-10V-2Fe-3Al alloy has been investigated. The Ti-10V-2Fe-3Al tensile specimens were solution treated at 700-900℃ and quenched to room temperature in water. All specimens, except the one solution treated at 700℃, experienced the SIMT when subjected to tensile deformation. The trigger stress was observed to initially decrease with the solution temperature increasing from 720℃ to 760℃. However, it increased with the temperature increasing from 760℃ to 900℃. Optical microstructure shows that with increasing solution temperature from 700℃ to 740℃, β grain size of Ti-1023 alloy kept invariable. However, recrystallization was observed when solution treated at 760℃. The recrystallized β grains grew larger and larger with increasing solution treatment temperature from 760℃ to 900℃. In addition, the volume fraction of primary alpha phase (α p ) always decreased with increasing ST temperature from 700℃ to 780℃. The microstructure was composed of only β single phase when solution treated from 830℃ to 900℃. Energy dispersive spectrometry (EDS) analysis indicates that the molybdenum equivalency (Mo eq ) of β matrix steeply decreased initially as solution temperature increased from 700 ℃ to 760 ℃ . However, it almost kept invariable with solution treatment temperature increasing from 760℃ to 900℃. This evolution in trigger stress was attributed to the variations of volume fraction of primary α phase, chemical composition of β phase and the β grain size with different solution treatment temperatures.