2021
DOI: 10.1039/d1ra03653j
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Effect of ZnO surface morphology on its electrochemical performance

Abstract: The purpose of this paper is to bridge the gap between ZnO surface morphology and its electrochemical performance.

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Cited by 16 publications
(8 citation statements)
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“…We also compared the capacitance of our electrode material with other works which use similar materials and electrolytes. Our V 2 O 5 /ZnO/FTO electrode shows a maximum areal capacitance of 3.3 mF cm −2 at 20.83 μA cm −2 , which is more than ZnO/ITO (0.65 mF cm −2 at 100 mV s −1 ), 32 ZnO/FTO (21 μF cm −2 at 50 mV s −1 ), 55 ZnO/MnO 2 /FTO (2.5 mF cm −2 at 0.1 mA cm −2 ), 56 SWCNT/ZnO (1.53 mF cm −2 at 1.25 μA cm −2 ), 3 and BR/P3HT/ITO (2.44 mF cm −2 at 20 μA cm −2 ). 57 We did not prefer carbon-based materials to improve the performance of the device to avoid the issues related to complex synthesis methods, loss of optical response, agglomeration of the material, and toxicity.…”
Section: Resultsmentioning
confidence: 66%
“…We also compared the capacitance of our electrode material with other works which use similar materials and electrolytes. Our V 2 O 5 /ZnO/FTO electrode shows a maximum areal capacitance of 3.3 mF cm −2 at 20.83 μA cm −2 , which is more than ZnO/ITO (0.65 mF cm −2 at 100 mV s −1 ), 32 ZnO/FTO (21 μF cm −2 at 50 mV s −1 ), 55 ZnO/MnO 2 /FTO (2.5 mF cm −2 at 0.1 mA cm −2 ), 56 SWCNT/ZnO (1.53 mF cm −2 at 1.25 μA cm −2 ), 3 and BR/P3HT/ITO (2.44 mF cm −2 at 20 μA cm −2 ). 57 We did not prefer carbon-based materials to improve the performance of the device to avoid the issues related to complex synthesis methods, loss of optical response, agglomeration of the material, and toxicity.…”
Section: Resultsmentioning
confidence: 66%
“…In addition, the impedance values of the seeded ZnO samples are lower than seedless ZnO and significantly lower than ITO, which can be ascribed to the higher surface exposure of n- ZnO with respect to the ITO electrodes. Nevertheless, the value of the ZnO impedance is correlated to the morphology of n- ZnO, with NSs being, in particular, able to reduce the impedance with respect to NWs . As a result, n- ZnO permits a significant reduction of the interfacial layer resistance, decreasing, in turn, the surface charge processes, which are essential in photocatalysis.…”
Section: Resultsmentioning
confidence: 99%
“…The gradual decrease in the charge transfer resistance of samples I 1 to I 4 (4.97 kΩ–35.1 Ω) is assigned to the improved film compactness and uniformity, along with the structural morphology from the nanocubes to nanoflowers. 70–72 At the onset potentials, the impedance spectra of I 1 and I 2 show large charge transfer resistance. This might be due to the lower surface compactness due to the nanocubic morphology.…”
Section: Resultsmentioning
confidence: 99%