Effect of water on the kinetics of the solid lithium-lithium ion reaction in propylene carbonate

Butler, James N.; Cogley, David R.; Synnott, John C.

doi:10.1021/j100845a082

Cited by 36 publications

(30 citation statements)

References 2 publications

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“…This exchange current density is in good agreement with exchange current densities measured for lithium in LiCIO~-PC electrolyte by Geronov et al (11), Butler et al (12), Scarr (13), and Moshtev (14). Although we were measuring current densities from the intercept of the straight line portion of a plot of log of the applied plating current vs. overpotential for lithium plating, an apparent quasi exchange current of 3 mA/cm ~ was calculated for deposition of lithium on a nickel electrode in both LiA1C14-3 SQ and 1.0M LiA1C14-SO~C12 electrolytes.…”

Section: Resultssupporting

confidence: 91%

Lithium Cycling Efficiencies in LiAlCl4 ‐ SO 2 and LiAlCl4 ‐ SO 2Cl2 Electrolytes

Walker

Binder

1988

J. Electrochem. Soc.

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Section: Resultssupporting

confidence: 91%

Lithium Cycling Efficiencies in LiAlCl4 ‐ SO 2 and LiAlCl4 ‐ SO 2Cl2 Electrolytes

Walker

Binder

1988

J. Electrochem. Soc.

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“…CO 2 and SO 2 are also employed as an additive for Li electrode to increase the Li cycling effi ciency. [ 128,129 ] The Li 2 CO 3 and Li 2 SO 3 passivation fi lms are generated from the reaction among CO 2 , SO 2 , and Li metal, respectively. However, the toxic property of SO 2 limits its broad applications in practical batteries.…”

Section: Additivesmentioning

confidence: 99%

A Review of Solid Electrolyte Interphases on Lithium Metal Anode

et al. 2015

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Lithium metal batteries (LMBs) are among the most promising candidates of high‐energy‐density devices for advanced energy storage. However, the growth of dendrites greatly hinders the practical applications of LMBs in portable electronics and electric vehicles. Constructing stable and efficient solid electrolyte interphase (SEI) is among the most effective strategies to inhibit the dendrite growth and thus to achieve a superior cycling performance. In this review, the mechanisms of SEI formation and models of SEI structure are briefly summarized. The analysis methods to probe the surface chemistry, surface morphology, electrochemical property, dynamic characteristics of SEI layer are emphasized. The critical factors affecting the SEI formation, such as electrolyte component, temperature, current density, are comprehensively debated. The efficient methods to modify SEI layer with the introduction of new electrolyte system and additives, ex‐situ‐formed protective layer, as well as electrode design, are summarized. Although these works afford new insights into SEI research, robust and precise routes for SEI modification with well‐designed structure, as well as understanding of the connection between structure and electrochemical performance, is still inadequate. A multidisciplinary approach is highly required to enable the formation of robust SEI for highly efficient energy storage systems.

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“…According to Dey [1] and Dousek et al [11], PC reacts with Li to form Li 2 co 3 • On the other hand, Butler et al [12] have demonstrated the predominant role of small amounts of water in the kinetics of fresh Li surfaces. As will be shown further, higher water amounts in the PC solutions increase secondary porous film formation.…”

Section: Film Thicknessmentioning

confidence: 99%

“…At the higher current densities (i.e., higher electric fields, above about 10 6 V/cm), a Tafel ) [8,12,13], and probably it is a capacitance of a surface layer formed in the glove box [16]. …”

Section: High-field Experimentsmentioning

confidence: 99%

Electrochemical Studies of the Film Formation on Lithium in Propylene Carbonate Solutions under Open‐Circuit Conditions

Geronov

Schwager

Müller

1982

J. Electrochem. Soc.

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The aim of this study is to investigate the kinetics of film formation on lithium in propylene carbonate solutions with different solutes and to determine some film characteristics such as resistance, conductivity, and thickness.Two principal ways of investigating these problems were chosen:electrochemical (galvanostatic pulse techniques) and optical (ellipsometry). This paper is dealing mainly with electrochemical measurements, while the results from ellipsometry will be presented

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Effect of water on the kinetics of the solid lithium-lithium ion reaction in propylene carbonate

Cited by 36 publications

References 2 publications

Lithium Cycling Efficiencies in LiAlCl4 ‐ SO 2 and LiAlCl4 ‐ SO 2Cl2 Electrolytes

Lithium Cycling Efficiencies in LiAlCl4 ‐ SO 2 and LiAlCl4 ‐ SO 2Cl2 Electrolytes

A Review of Solid Electrolyte Interphases on Lithium Metal Anode

Electrochemical Studies of the Film Formation on Lithium in Propylene Carbonate Solutions under Open‐Circuit Conditions

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