“…Theoretical modeling provides an essential insight into the atomic structure and nanoscale phenomena, which has become a significant means for complementing experiments. Quantum mechanical calculations, such as density functional theory (DFT) [16,17], are routinely used to investigate and understand the structural, magnetic, mechanic, optical, and electronic properties of many different materials [18][19][20]. For structure property calculations of our CuPPD crystal, we selected the generalized gradient approximation (GGA) correlation energy functionals (XC) in the form parameterized by Perdew-Burke-Ernzerhof (PBE) [21], which remains the most satisfactory for solids containing 3d transition elements [22].…”