The current investigation
deals with the treatment of water pollution
that is caused by the leaching of nickel ions from the metallurgical
industry and new-energy batteries. Therefore, an eco-friendly treatment
of nickel through the use of a composite of cotton stalk biochar with
nanozerovalent copper has been presented in this investigation signifying
the impact of zerovalent copper in enhancing the adsorption capacity
of biochar for nickel adsorption. Thermogravimetric analysis data
showed the adsorbent to be significantly stable in the higher thermal
range, whereas transmission electron microscopy analysis confirmed
the particles to be 27 nm and also showed the cubic geometry of the
particles. A much closer scanning electron microscopy analysis shows
the morphology of particles to be cubic in shape. Batch adsorption
indicated a positive influence of pH increase on adsorption due to
the electrostatic attraction between positive nickel ions and post
point of zero charge (pHPZC) negative surface of copper
biochar composite (pH > 5.5). A high adsorption rate was observed
in the first 60 min, whereas adsorption increased with the increase
in temperature from 303 to 318 K. Kinetic modeling confirmed the pseudo-first-order
to fit best to the data. The apparent activation energy (11.96 kJ
mol–1) is indicative of the chemical nature of the
process. The adsorption data fitted well to the Langmuir adsorption
model. The negative values of apparent ΔG°
and the positive values of apparent ΔH°
indicate the spontaneity and endothermicity of the process, respectively,
whereas the positive values of apparent ΔS°
point toward increased randomness during the process. Postadsorption
XPS suggests the adsorption of nickel on the surface of biochar composites
in the form of Ni(OH)2 and NiO(OH).