“…The addition of blowing agents changes the porosity from nanometric and meso to nanometric, meso and ultra-macro sizes. Hydrogen peroxide as blowing agent [5], redox reaction of aluminum powder in alkaline solution [4,9] or that of metallic Si [5][6][7][8] have been used as low temperature, low-energy , environmentally-friendly and sustainable processes for the production of ultra porous inorganic matrices in comparison to the high temperature treatment for burnout of fugitive additives and sintering with the aim to achieve porous ceramics [5][6][7][8][9][10][11][12]. Although the effective possibility of the above techniques to be used for the production of porous inorganic polymer without thermal treatment, the final products still suffer homogeneity and the difficulty for the control of the pore shape, pore size and correlation of the properties of the fresh paste to the final microstructure in relation with the bulk chemical composition of the initial formulation.…”