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“…By 2023, the global market of cyclopentane is expected to reach US$ 335.7 million, with an annual growth rate of 6.7% . Cyclopentane resource has been detected in light petroleum fractions like naphtha , and natural gas liquid; however, it is hardly separated as a commercial grade product through traditional fractionation operations owing to the formation of close-boiling/azeotropic mixtures with hydrocarbons possessing similar numbers of carbon atoms. Neohexane or 2,2-dimethylbutane (22DMB) is a major contaminant in cyclopentane.…”
Section: Introductionmentioning
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“…By 2023, the global market of cyclopentane is expected to reach US$ 335.7 million, with an annual growth rate of 6.7% . Cyclopentane resource has been detected in light petroleum fractions like naphtha , and natural gas liquid; however, it is hardly separated as a commercial grade product through traditional fractionation operations owing to the formation of close-boiling/azeotropic mixtures with hydrocarbons possessing similar numbers of carbon atoms. Neohexane or 2,2-dimethylbutane (22DMB) is a major contaminant in cyclopentane.…”
Section: Introductionmentioning
“…It is also a high-quality blending component for clean gasoline with high octane number. , The composition of cyclopentane-neohexane from naphtha varies widely in volume from 92/8 to 29/71 . The discrimination of these two compounds is a great challenge because they not only exhibit extremely close boiling points of only 0.4 K difference but also form azeotropic components. , Considering the impossibility of splitting neohexane from cyclopentane by simple distillation operations, azeotropic and extractive distillations , have been designed to produce cyclopentane of higher purities. However, these heat-driven distillation-based hydrocarbon separations represent the most energy-intensive and operationally complex processes .…”
Section: Introductionmentioning
“…Lee and Ronald 9 purified cyclohexane from a mixture of 85 wt % cyclohexane and 15 wt % 2,3-dimethylpentane using various mixed entrainers. Other works using mixed entrainer included Brown and Lee 10 and Song et al 11 Recently, Lavanya et al 12 reported the production of cyclopentane by extractive distillation. However, the previous works mentioned above are focused on hydrocarbon mixture of C 5 -C 7 .…”
Section: Introductionmentioning
“…N-(β-mercaptoehtyl)-2-pyrrolidone (NMEP), cyclohexanol (CHOL), N-methyl-pyrrolidone (NMP), or a mixture of NMEP and either CHOL or NMP, phenol and NMP+5% water [6], [7]. Among these solvents, mixed solvent tends to be more effective than single solvent, since single solvent cannot have high selectivity and solubility simultaneously.…”
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