1964
DOI: 10.5006/0010-9312-20.9.293t
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Effect of Plastic Deformation On the Corrosion of Iron and Steel

Abstract: Cold work markedly decreases the corrosion resistance of steel in acid solutions. This effect has been studied by electrochemical measurements and weight loss tests on zone-refined iron and carbon steels exposed to sulfuric and hydrochloric acids. The mechanism of this phenomenon is discussed in detail.

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Cited by 71 publications
(30 citation statements)
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“…The deformation process causes the modification of the microstructure: after cold working, the occurrence of residual stress and the formation of the Strain-Induced Martensite (SIM) from the metastable austenite can substantially affect the pitting resistance of duplex stainless steels, because the number of the active anodic sites on the surface increases [46,47]. Thickness, composition, and uniformity of the passive layer are modified in different extent by plastic deformation [48,49] and the increasing in dislocation density favors the film dissolution due to the presence of lower binding energy regions, compared to a perfect crystal [50]. This may affect the formation of a less effective passive film on the steel surface; moreover, the presence of distorted high-energy interfaces may provide further trigger points for the localized attack [51,52].…”
Section: Corrosion Pitting Temperature (Cpt)mentioning
confidence: 99%
“…The deformation process causes the modification of the microstructure: after cold working, the occurrence of residual stress and the formation of the Strain-Induced Martensite (SIM) from the metastable austenite can substantially affect the pitting resistance of duplex stainless steels, because the number of the active anodic sites on the surface increases [46,47]. Thickness, composition, and uniformity of the passive layer are modified in different extent by plastic deformation [48,49] and the increasing in dislocation density favors the film dissolution due to the presence of lower binding energy regions, compared to a perfect crystal [50]. This may affect the formation of a less effective passive film on the steel surface; moreover, the presence of distorted high-energy interfaces may provide further trigger points for the localized attack [51,52].…”
Section: Corrosion Pitting Temperature (Cpt)mentioning
confidence: 99%
“…Past investigations on cold working of pure Fe with subsequent annealing have been found to impact the grain size evolution [17], corrosion rate in acidic media [18,19] and mechanical properties [20]. Nevertheless, the effect of BD on microstructural changes, mechanical properties and degradation behaviours of pure Fe was not thoroughly addressed in previous studies particularly in relation to crystallographic texture [12] and recrystallization behaviour [21].…”
Section: Introductionmentioning
confidence: 96%
“…Literature review indicates that numerous previous work was devoted to understanding the effect of plastic deformation on the corrosion resistance of aluminum alloys, copper, and steels . Nevertheless, most of the work focused mainly on the influence of deformation at macroscopic scale, with little attention paid to the effect of LPD on corrosion mechanism.…”
Section: Introductionmentioning
confidence: 99%