A knock-on tail formation in deuteron velocity distribution function due to nuclear elastic scattering (NES) by energetic protons and its observation method using γ-ray-generating 6 Li(d,pγ) 7 Li reaction are examined for proton-beam-injected deuterium plasmas. The proton velocity distribution function is obtained by means of the ion trajectory analysis in a Tokamak magnetic configuration. The knock-on tail in two-dimensional (2D) deuteron velocity distribution function due to NES by energetic protons is evaluated via Boltzmann collision integral and 2D Fokker-Planck simulation. From the 2D deuteron velocity distribution function obtained, enhancement of the emission rate of 0.48-MeV γ-rays by 6 Li(d,p) 7 Li*, 7 Li*→ 7 Li+γ reaction due to NES is evaluated. It is shown that the γ-ray emission rate is significantly influenced by the magnitude of the knock-on tail, and the γ-ray-generating reaction can be a useful tool for the knock-on tail observation.