Effect of Mixing of Metal Cations on the Topology of Metal Oxide Networks

Livage, Carine; Forster, Paul M.; Guillou, Nathalie; Tafoya, Maya M.; Cheetham, Anthony K.; Férey, Gérard

doi:10.1002/ange.200700247

Cited by 15 publications

(4 citation statements)

References 36 publications

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“…In this way, ligands having different donor atoms can coordinate metal ions of different Lewis acidity and coordination geometry forming a MM‐MOF . MM‐MOFs in which two different metals are presented in a certain proportion range have been reported to be prepared using synthetic procedures common in MOF synthesis, such as conventional heating and solvothermal procedures . Depending on the synthesis conditions and the nature and proportion of the various metal precursors the resulting MM‐MOF can be derived from the thermodynamic or kinetic control and this may influence the distribution and location of the metals.…”

Section: Synthetic Strategies For Preparation Of Mm‐mofsmentioning

confidence: 99%

Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design

et al. 2019

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MOFs are synthesized following al arge variety of procedures,i ncluding solvo/hydro thermal methods,s low diffusion, conventional heating, slow evaporation, mechanochemical, and sonochemical. [28][29][30][31][32] Several of these synthetic Mixed-metal metal-organic frameworks (MM-MOFs) can be considered to be those MOFs having two different metals anywhere in the structure.H erein we summarizethe various strategies for the preparation of MM-MOFs and some of their applications in adsorption, gas separation, and catalysis.I ti sshown that compared to homometallic MOFs,MM-MOFs bring about the opportunity to take advantage of the complexity and the synergism derived from the presence of different metal ions in the structure of MOFs.This is reflected in as uperior performance and even stability of MM-MOFs respect to related single-metal MOFs.Emphasis is made on the use of MM-MOFs as catalysts for tandem reactions.

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Section: Synthetic Strategies For Preparation Of Mm‐mofsmentioning

confidence: 99%

Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design

et al. 2019

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“…Further focal points of his research are magnetism and fluorine chemistry. He recently reported in Angewandte Chemie on the grafting of amines on coordinatively unsaturated metal centers of metal–organic frameworks1a and on the effect of mixing metal cations on the topology of metal oxide networks 1b…”

Section: Awarded…︁mentioning

confidence: 99%

New applications and developments in the use of multiplex ligation‐dependent probe amplification

2008

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Multiplex ligation-dependent probe amplification (MLPA) is a commonly used technique for determining relative DNA sequence dosage (or copy number) in a complex DNA sample. Originally MLPA was designed as a copy number analysis tool for detecting disease-causing genomic mutations and has been successfully applied in the testing and identification of hundreds of genomic mutations in numerous genes including DMD, BRCA1, NF1, and TSC2. More recently, several modifications of the original technique have been implemented. Arguably the most important enhancement of MLPA has been probe generation by chemical synthesis, enabling the facile creation of novel probe sets for any desired application. Other newer applications of MLPA include methylation status determination, copy number analysis in segmentally duplicated regions, expression profiling, and transgene genotyping. MLPA has a potential major role in the analysis of common copy number variation in genome-wide association analyses, which may be enhanced by future improvements to increase throughput and lower costs, such as array-MLPA.

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“…Weitere Schwerpunkte seiner Arbeiten sind der Magnetismus und die Fluorchemie. Kürzlich berichtete er in der Angewandten Chemie über die Verknüpfung von Aminen mit koordinativ ungesättigten Metallzentren in metallorganischen Gerüsten1a und über den Einfluss der Vermischung von Metallkationen auf die Topologie von Metalloxidnetzwerken 1b…”

Section: Ausgezeichnet…︁unclassified

Anorganische Chemie: G. Férey ausgezeichnet / Metallorganische Chemie: Knochel geehrt / Materialwissenschaften: Preis für Mallouk /

2008

Angewandte Chemie

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Effect of Mixing of Metal Cations on the Topology of Metal Oxide Networks

Cited by 15 publications

References 36 publications

Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design

Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design

New applications and developments in the use of multiplex ligation‐dependent probe amplification

Anorganische Chemie: G. Férey ausgezeichnet / Metallorganische Chemie: Knochel geehrt / Materialwissenschaften: Preis für Mallouk /

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