“…Microwave treatment on starch were carried out especially on samples with high water content, over 20%, and less on samples with low (1 -5%) or limited (7 -15%) moisture content. The results showed that microwaves may determine the rearrangement of intermolecular structure indicating that the starch granule structure is disintegrated and, consequently, they lead to slight reduction of the water absorption ability, of solubility and swelling power as well as changes of the gelatinization temperature, syneresis or paste viscosity (Lewandowicz et al, 1997;Lewandowicz et al, 2000;Gonzalez & Perez, 2002;Gonzalez Parada & Perez Sira, 2003;Szepes et al, 2005;Luo et al, 2006;Lares & Perez, 2006) strongly correlated with experimental treatment parameters. Starch exposed to electrical discharges (plasma) may suffer either crosslinking phenomenon (Zou et al, 2004 or depolymerization to dextrins with different molecular weights (Lii et al, 2002a;Lii et al, 2002b) …”
“…Microwave treatment on starch were carried out especially on samples with high water content, over 20%, and less on samples with low (1 -5%) or limited (7 -15%) moisture content. The results showed that microwaves may determine the rearrangement of intermolecular structure indicating that the starch granule structure is disintegrated and, consequently, they lead to slight reduction of the water absorption ability, of solubility and swelling power as well as changes of the gelatinization temperature, syneresis or paste viscosity (Lewandowicz et al, 1997;Lewandowicz et al, 2000;Gonzalez & Perez, 2002;Gonzalez Parada & Perez Sira, 2003;Szepes et al, 2005;Luo et al, 2006;Lares & Perez, 2006) strongly correlated with experimental treatment parameters. Starch exposed to electrical discharges (plasma) may suffer either crosslinking phenomenon (Zou et al, 2004 or depolymerization to dextrins with different molecular weights (Lii et al, 2002a;Lii et al, 2002b) …”
“…Therefore, the increase of gelatinization temperature observed in moistened treated flours would be in agreement with XRD results. The rise in gelatinization temperatures has also been associated with the formation of amyloseamylose and amylose-lipid complexes within the starch granule and an association and a more stable configuration in the granular structure (Lewandowicz et al 2000). A slight but significant decrease in the gelatinization enthalpy of the microwaved-treated flours was observed probably because the samples underwent a partial gelatinization as a consequence of microwave treatment.…”
Section: Effect Of Microwave Treatment On Thermal Properties Of Rice mentioning
The microwave radiation thermal treatment of rice flour was studied and its impact on physical and structural characteristic in relation to the initial moisture content (IMC) (20% and 30%) was evaluated. To explain the fundamentals of observed changes the microwave radiation absorption capacity of flour as well as temperature and moisture change during the treatment were evaluated. The flour particle morphological structure as well as crystallinity/amorphous region ratio changed after the treatment. The flour thermal properties also altered revealing IMC significant impact on the gelatinization temperature, that rised up to 3ºC, and the amylopectin retrogradation extent that increased up to a 7% in the most intense microwave-treated flours with respect to the native flour. Lower peak, setback and breakdown viscosities -that decreased with respect to the native flour up to 42%, 34% and 86% respectively-and higher pasting temperatures -that increased up to 10 ºC-were also observed. An exceptional microwave irradiation efficiency resulting in rice flour physical changes in significantly shorter times, 4-8 min, than conventional heat-moisture treatment processes was concluded.
“…However, phosphorylation considerably lowered the pasting temperature, and copper-enriched spelt monostarch phosphate had the lowest pasting temperature of all the starches investigated (Table 3). A change of certain pasting properties of examined starches, including pasting temperature (Table 3) may be affected by changes in the crystal structure during process of starch modification as Lewandowicz et al (2000) reported for wheat and corn starches. Copper(II) enrichment resulted in increased values of peak viscosity (PV), trough (TV), final viscosity (FV) and setback (SB) compared with the natural starch; this was in contrast to the corresponding values obtained following iron(II) enrichment, which were lower than those for natural starch (Table 3).…”
Section: Dsc Of the Thermodynamic Propertiesmentioning
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