Ceramic
phase reinforced aluminum matrix composites (CAMCs) are
widely used in high-tech fields represented by aerospace industry
due to their advantages of high specific strength, high specific modulus,
high thermal stability, and light weight. Strong interface bonding
is a prerequisite for high performance of multiphase materials. Herein,
a novel CAMC in situ reinforced by MgAl2O4 particles
and MgAlB4 nanorods was prepared by vacuum hot-pressing
combined with hot-extrusion process. A high-resolution transmission
electron microscope was used to characterize the orientation relationship
and interface structure between the ceramic phases and the aluminum
matrix. Two orientation relationships (OR1 and OR2) of MgAl2O4/Al and one (OR3) of MgAlB4/Al are determined:
OR1-[011]p//[011]Al, (11̅1)p//(11̅1)Al; OR2-[211]p//[011]Al, (113̅)p//(022̅)Al; OR3-[101̅0]R//[001]Al, (0002)R//(2̅20)Al. The MgAl2O4 in OR1 forms a coherent
interface with the aluminum matrix at (111) surface, while they form
a 4 × 5 near coincidence site lattice (CSL) interface structure
for OR2. In OR3, the MgAlB4 forms an approximate coherent
interface with Al matrix at its (0002) surface and a 2 × 5 CSL
interface structure at its (011̅0) surface. First-principles
calculations suggest that MgAl2O4 combines to
aluminum at (111) plane through covalent bonds, which means high interfacial
bonding strength. The hot-extrusion process makes the ceramic phase
evenly distributed in the matrix. The mechanical properties of the
composites are greatly improved compared with pure aluminum.