1995
DOI: 10.1007/bf02606670
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Effect of Gd3+ ions on the luminescence of opa-Gly

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Cited by 3 publications
(2 citation statements)
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“…For this reason, it makes a big difference if the paramagnetic effect is involved or not in calculations. Clearly, this finding suggests that the fluorescence quenching mechanism is not solely dependent on the enhancement of the rate of ISC ( k ISC ) in the paramagnetic metal complexes as reported previously , but also on the decrement of the fluorescence emission rate constant k f induced by the paramagnetic effect.…”
Section: Resultssupporting
confidence: 78%
See 1 more Smart Citation
“…For this reason, it makes a big difference if the paramagnetic effect is involved or not in calculations. Clearly, this finding suggests that the fluorescence quenching mechanism is not solely dependent on the enhancement of the rate of ISC ( k ISC ) in the paramagnetic metal complexes as reported previously , but also on the decrement of the fluorescence emission rate constant k f induced by the paramagnetic effect.…”
Section: Resultssupporting
confidence: 78%
“…Actually, there are a limited number of studies on this topic, and most of them have just ascribed the fluorescence quenching mechanism for the Gd­(III) complexes to the significant enhancement of the ISC (S 1 → T 1 ) rate. Nevertheless, the reported reasons of the ISC rate increase for these Gd­(III) complexes in the literature are quite confusing and sometimes controversial since the ISC rate enhancement can be caused by anyone of the paramagnetic effect and the heavy-atom effect alone or their combination . In other words, a certain conclusion could be drawn that the paramagnetic effect can modify the emission properties of the Gd­(III) metal complexes and is different from the heavy-atom effect.…”
Section: Introductionmentioning
confidence: 99%