“…High population density and reliance on automobile transportation lead to the development of large spatial gradients in gaseous and particulate N pollutants, the majority (85-95%) of which fall as dry deposition during the summer when inversion conditions trap these pollutants near the land surface (Bytnerowicz and Fenn, 1996;Fenn et al, 2003a). Annual inputs of atmospheric N to exposed urban shrublands are on the order of 25-50 kg N/ha (Bytnerowicz and Fenn, 1996;Fenn et al, 2003a;Riggan et al, 1985); however, the spatial pattern of N deposition is highly variable and poorly understood and sites at slightly higher elevations can receive up to 145 kg N/ha y (Fenn and Poth, 2004 the capacity to significantly alter the N and C storage and cycling of chaparral ecosystems, which are considered to be N-limited (Fenn et al, 2003b;Gray and Schlesinger, 1983;Kummerow et al, 1982). For example, atmospheric N inputs can increase total and available N through direct fertilization and enhanced mineralization, reduce soil and vegetation C:N ratios, enhance soil acidification, and promote losses of N from gaseous efflux and leaching (Fenn et al, 2003b;Meixner and Fenn, 2004;Michalski et al, 2004;Padgett et al, 1999;Riggan et al, 1985;Vourlitis et al, 2007a, b).…”