Abstract:Corrosion behavior of X70 steel under the application of dynamic DC stray current was investigated in simulated soil solution by immersion tests and electrochemical measurements. Experimental results indicated that the corrosion rate of X70 steel under dynamic DC stray current was strongly influenced by the dynamic period. When the dynamic period was <80 s, the corrosion rate was only approximately 1–7% of that caused by an equivalent amount of steady direct current. However, as the dynamic period became &g… Show more
“…At present, research on the influence of current on metal corrosion has been carried out to a certain extent, especially the influence mechanism of DC current on the corrosion behavior of metal has obtained some highly recognized conclusions. Research by Zhang et al [16] and Qin et al [17] shows that under the action of the DC electric field, the corrosion of metal materials is accelerated, and the corrosion rate is proportional to the current density. However, the mechanism of AC current corrosion is still worth discussing, especially, the effect of current density on the corrosion rate is relatively complex.…”
Cu–Al composite plate corrosion tests, under a 0–100 A AC current, were conducted for 48 hr in a neutral salt spray. The morphology and corrosion products were studied by scanning electron microscope and X‐ray powder diffraction, through which the effect of the current was analyzed. Meanwhile, the rate and degree of corrosion were evaluated by weight loss, electrochemical and electrolytic conductivity detection methods. The results showed that when the current increased, the corrosion rate initially increased and then decreased. When the current value was 50 A, the corrosion rate was the highest. The corrosion of the Cu–Al composite plate mainly included galvanic corrosion at the interface and pitting on the aluminum matrix, with no corrosion on the copper matrix. The state of the passivation film changed to loose, peeling, rupture, accumulation, compact, and so on when the current value increased. The type of corrosion product was not affected by the current value. The current affects the electromobility of the chloride ions by influencing the conductivity of the corrosion medium. The higher the electromobility of the chloride ions, the less the destruction of the passivation film and as a result, there is a decreased rate and degree of corrosion.
“…At present, research on the influence of current on metal corrosion has been carried out to a certain extent, especially the influence mechanism of DC current on the corrosion behavior of metal has obtained some highly recognized conclusions. Research by Zhang et al [16] and Qin et al [17] shows that under the action of the DC electric field, the corrosion of metal materials is accelerated, and the corrosion rate is proportional to the current density. However, the mechanism of AC current corrosion is still worth discussing, especially, the effect of current density on the corrosion rate is relatively complex.…”
Cu–Al composite plate corrosion tests, under a 0–100 A AC current, were conducted for 48 hr in a neutral salt spray. The morphology and corrosion products were studied by scanning electron microscope and X‐ray powder diffraction, through which the effect of the current was analyzed. Meanwhile, the rate and degree of corrosion were evaluated by weight loss, electrochemical and electrolytic conductivity detection methods. The results showed that when the current increased, the corrosion rate initially increased and then decreased. When the current value was 50 A, the corrosion rate was the highest. The corrosion of the Cu–Al composite plate mainly included galvanic corrosion at the interface and pitting on the aluminum matrix, with no corrosion on the copper matrix. The state of the passivation film changed to loose, peeling, rupture, accumulation, compact, and so on when the current value increased. The type of corrosion product was not affected by the current value. The current affects the electromobility of the chloride ions by influencing the conductivity of the corrosion medium. The higher the electromobility of the chloride ions, the less the destruction of the passivation film and as a result, there is a decreased rate and degree of corrosion.
The corrosion behavior of X70 steel in simulated soil environment under asymmetric dynamic direct current (DC) interference was studied by immersion tests. The experimental results showed that the negatively asymmetric dynamic DC interference would induce localized corrosion. Under the same dynamic period of 160 ±80 s, when the negative half-wave current density remained stable at −10 mA/cm 2 and the positive half-wave one decreased from 7 to 1 mA/cm 2 , the equivalent diameters of the localized corrosion zones became smaller and the steel samples demonstrated typical pitting corrosion morphologies. To further explore the effect of asymmetric dynamic DC interference on the localized corrosion behavior of carbon steel, a variety of experimental measurements were carried out including real-time DC potential monitoring, in-situ near-surface pH measurements, cyclic voltammetry, and Mott-Schottky tests. It was found that the localized corrosion behavior was probably related to the breakdown of passive film formed on the metal surface exposed to negatively asymmetric DC current generated high pH conditions.
To provide a reference for the evaluation of corrosion rate under dynamic metro stray current, both simulated experiments in laboratory and coupon tests in the field were conducted to explore the corrosion behavior and the relationship between corrosion rates and dynamic DC interference parameters of buried pipelines. The results show that the dynamic period has a significant influence on the corrosion rate and the ratio of actual corrosion rate to the theoretical corrosion rate. The statistical data of pipe to soil potentials or current densities of coupons electrically connected to pipelines obtained from the field in many cities of China show that the dynamic fluctuation periods under metro stray current are within the range of 0–300 s, among which the majority of fluctuation periods distribute from 50 to 200 s. The dynamic fluctuation of pipe to soil potentials and current densities of coupons exhibits symmetric or asymmetric characteristics. Under the situation of symmetric positive and negative current density, the ratio of the actual corrosion rate to the theoretical corrosion rate ranges from about 4% to 22% under the typical dynamic periods range from 50 to 200 s based on the simulated experiments results in the laboratory. Besides, two corrosion rate assessment methods, including the positive shifting and time ratios of off‐potentials and symmetrical or asymmetric characteristics of DC current density of coupons were proposed. In addition, the evaluation of the on‐potential criteria to assess the corrosion risk of time‐variant anodic interference was also discussed in the paper.
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