Abstract:This contribution presents results of comprehensive investigation of the E-H transition in an inductively coupled radio frequency argon/oxygen discharge at 13.56 MHz. For the characterization of the discharge arrangement, the spatial magnetic and electric field components of the planar coil in vacuum are calculated and provide information about the electron heating region. The used double coil leads to a radial symmetric field distribution. Further, voltage and current probe measurements reveal the inductivity… Show more
“…rotational temperatures determined by O 2 OES gave the same value for pure O 2 and O 2 with 15% Ar plasmas. This is in line with measurements by Wegner et al 29) of ion saturation current, line-integrated electron density and E-H mode transition voltages for a range of Ar/O 2 mixtures in a 10 Pa ICP. For pure O 2 and 25% Ar, the values are within roughly 10% of each other, giving some confidence that also the gas temperature is minimally affected by the admixture.…”
Section: Optical Emissions Spectroscopy Of Thesupporting
Optical emission spectroscopy (OES) of the magnetic dipole allowed O2(b1Σg
+) to O2(X3Σg
−) transition was investigated as a non-intrusive gas temperature diagnostic for E-mode and H-mode inductively coupled plasmas (ICP) in oxygen. It was compared to tunable diode laser absorption spectroscopy using Ar admixtures, and OES of the nitrogen Second Positive System with nitrogen admixtures. O2 OES provided accurate results for the E-mode ICP, 400–600 K for powers of 100–300 W, but in H-mode the method was unsuitable probably because of excitation of O2(b1Σg
+) by metastable atomic oxygen. Rotational temperatures were measured, using N2 OES with N2 admixtures, for pulsed operation of the ICP with a 30 ms pulse duration and 15% duty cycle. It took 1–3 ms before the steady-state rotational temperatures were achieved. In addition, a small variation of matching network settings affects the plasma ignition delay time by several ms.
“…rotational temperatures determined by O 2 OES gave the same value for pure O 2 and O 2 with 15% Ar plasmas. This is in line with measurements by Wegner et al 29) of ion saturation current, line-integrated electron density and E-H mode transition voltages for a range of Ar/O 2 mixtures in a 10 Pa ICP. For pure O 2 and 25% Ar, the values are within roughly 10% of each other, giving some confidence that also the gas temperature is minimally affected by the admixture.…”
Section: Optical Emissions Spectroscopy Of Thesupporting
Optical emission spectroscopy (OES) of the magnetic dipole allowed O2(b1Σg
+) to O2(X3Σg
−) transition was investigated as a non-intrusive gas temperature diagnostic for E-mode and H-mode inductively coupled plasmas (ICP) in oxygen. It was compared to tunable diode laser absorption spectroscopy using Ar admixtures, and OES of the nitrogen Second Positive System with nitrogen admixtures. O2 OES provided accurate results for the E-mode ICP, 400–600 K for powers of 100–300 W, but in H-mode the method was unsuitable probably because of excitation of O2(b1Σg
+) by metastable atomic oxygen. Rotational temperatures were measured, using N2 OES with N2 admixtures, for pulsed operation of the ICP with a 30 ms pulse duration and 15% duty cycle. It took 1–3 ms before the steady-state rotational temperatures were achieved. In addition, a small variation of matching network settings affects the plasma ignition delay time by several ms.
“…The transition between capacitive and inductive mode is usually abrupt and occurs when the discharge power reaches a certain value, which depends on peculiarities of a particular discharge configuration. Such transitions have been studied for many gases by different authors …”
Section: Introductionmentioning
confidence: 99%
“…Such transitions have been studied for many gases by different authors. [1][2][3][4][5][6] Plasma created by electrodeless discharges represents a rich source of reactive gaseous species. As in many other types of discharges, the gaseous molecules are excited, dissociated or/and ionized upon interacting with electrons from the high-energy part of their distribution function.…”
Characteristics of ammonia plasma sustained by inductively coupled radiofrequency discharge has been studied in the range of powers between 50 and 1000 W and pressures between 10 and 90 Pa. In such an experimental setup pronounced differences between the E‐ and H‐mode were observed and explained to some details. Plasma was characterized by optical emission spectroscopy (OES) and residual gas spectrometry (RGA). The plasma luminosity changed for four orders of magnitude and the NH2 band vanished at higher powers (H‐mode). The RGA results indicated high density of NH2 radicals in the E‐mode while in the H‐mode the ammonia molecules almost entirely dissociated to H and N atoms. The N and H atoms created in the plasma recombined to the nitrogen and hydrogen molecules rather than to parent ammonia molecules on the way to the RGA.
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