Dynamic Combinatorial Chemistry in Drug Discovery, Bioorganic Chemistry, and Material Science. Edited by Benjamin L. Miller.

Link, Andreas

doi:10.1002/cmdc.201000110

Cited by 2 publications

(1 citation statement)

References 10 publications

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“…It is well-known that guest-induced self-assembly of host compounds based on a suitable bonding motif has become a reliable method to recognize specific guest molecules, mainly including dynamic covalent bonding − or reversible metal–ligand coordination. − Particularly, the N → B bond mediated by Lewis acid/base interactions between boronate esters and nitrogen nucleophiles provides a unique potential in host–guest chemistry, because it is suitable to achieve strong but also reversible supramolecular assemblies. The inspiring work reported by Iwasaws et al can release and recover guest molecules during the reversible borate gel formation of guest-included macrocyclic boronic esters .…”

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Separation and Purification of Xylene by Self-Assembly of a Tunable N → B Adduct

Wang

Liu

et al. 2021

Crystal Growth & Design

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It is challenging to obtain isomers in a pure form because of the similarities in their physicochemical properties. meta-Xylene (MX) accounts for the largest proportion of commercial xylene, which is difficult to separate from xylene through low-temperature crystallization and fractionation or adsorbents. In this work, the synthesis of the N → B adduct with preferential selectivity to meta-xylene is obtained by the combination of 1,4-bis(benzodioxaborole)benzene and 1,2-di(4-pyridyl)ethylene in a molar ratio of 1:1. The high selectivity to MX of the N → B adduct may be mainly attributed to the lower energy of the trans-structure of the two catecholate groups. Also, the forces between the guest and the host molecule influence the selectivity. In the liquid xylene mixture, the selective order of the N → B adduct is meta-xylene > ortho-xylene > para-xylene. And the N → B adduct can be reused without losing capture capacity.

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confidence: 99%

Separation and Purification of Xylene by Self-Assembly of a Tunable N → B Adduct

Wang

Liu

et al. 2021

Crystal Growth & Design

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Novel Electrolytic Processes

Mitsudo

2022

Sustainable and Functional Redox Chemistry

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This chapter describes the recent advances in electrochemical processes used for organic synthesis, including parallel batch systems and flow systems. Parallel batch systems allow simultaneous electrochemical reactions to be performed with multiple batches, and flow systems allow efficient sequential syntheses to be carried out by changing the substrates pumped into the flow reactor. The use of bipolar electrodes, which are not connected to the electrodes, has enabled the production of polymer brushes and microfibers with patterned gradients.

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Dynamic Combinatorial Chemistry in Drug Discovery, Bioorganic Chemistry, and Material Science. Edited by Benjamin L. Miller.

Cited by 2 publications

References 10 publications

Separation and Purification of Xylene by Self-Assembly of a Tunable N → B Adduct

Separation and Purification of Xylene by Self-Assembly of a Tunable N → B Adduct

Novel Electrolytic Processes

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