2014
DOI: 10.1021/ef4020845
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Durability of CaO–CaZrO3 Sorbents for High-Temperature CO2 Capture Prepared by a Wet Chemical Method

Abstract: eprints@whiterose.ac.uk https://eprints.whiterose.ac.uk/ Reuse Unless indicated otherwise, fulltext items are protected by copyright with all rights reserved. The copyright exception in section 29 of the Copyright, Designs and Patents Act 1988 allows the making of a single copy solely for the purpose of non-commercial research or private study within the limits of fair dealing. The publisher or other rights-holder may allow further reproduction and re-use of this version -refer to the White Rose Research Onlin… Show more

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Cited by 91 publications
(60 citation statements)
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“…Several techniques have been proposed in previous works such as precipitation methods, 5,6 organic acid treatments, [7][8][9][10][11] chemical doping, 12,13 hydration, 12,[14][15][16][17] and synthesis techniques of highly efficient sorbents, i.e. sol-gel method, [18][19][20][21] carbon template, 19,22 and biomass template.…”
Section: Introductionmentioning
confidence: 99%
“…Several techniques have been proposed in previous works such as precipitation methods, 5,6 organic acid treatments, [7][8][9][10][11] chemical doping, 12,13 hydration, 12,[14][15][16][17] and synthesis techniques of highly efficient sorbents, i.e. sol-gel method, [18][19][20][21] carbon template, 19,22 and biomass template.…”
Section: Introductionmentioning
confidence: 99%
“…One promising method is the development of highly efficient sorbents to improve long-term performance [8][9][10][11][12][13][14][15][16][17][18][19][20]. The other is using simple reactivation routes to reduce the rate of decay in reactivity [3,[21][22][23].…”
Section: Introductionmentioning
confidence: 99%
“…As mentioned in the Introduction, there is a wide literature on other high‐temperature powder sorbents for CO 2 capture, most notably for CaO powders in which refractory additives are introduced, for example, ZrO 2 to suppress the natural densification (partial sintering) and loss of porosity that degrades cycle on cycle the CaO performance, as outlined in the Introduction. Often, very complex chemical solution precipitation reactions are employed to promote adequate mixing of the two components.…”
Section: Resultsmentioning
confidence: 99%
“…A uniform distribution of the second phase is essential to minimize densification of the active CaO phase and suppress multicycle degradation. The performance of a range of CaO‐based sorbents is summarized in the study of Zhao et al . The more complex (and costly) the processing technique, for example, sol‐gel or chemical templating, the finer the particle size, and the more uniform the dispersion.…”
Section: Introductionmentioning
confidence: 99%