recent years to alleviate the global energy shortage and environmental pollution. They have promising applications as sustainable power sources for widely distributed sensor networks in the new era of the Internet of Things (IoT). The clean raindrop and solar energies both possess merits of wide distribution and high energy density, but they are closely related to the weather conditions. In this regard, combining them to realize complementary energy collection has been proven to be one of the effective solutions to achieve all-weather and sustainable energy supply. Due to the characteristics of widespread distribution, low frequency and limited driving force, the raindrop energy cannot be effectively harvested by traditional hydraulic power generator, which is usually heavy, bulky, and needs larger driving force to achieve high conversion efficiency at high frequency. [1] Since the invention of triboelectric nanogenerator (TENG) in 2012, [2] it has been extensively investigated because of the advantages of light weight, small size, wide material selection, low cost, [3][4][5] and even high efficiency at low frequency, [6] etc., and provides an effective approach for converting raindrop energy into electricity.Previous raindrop TENGs (R-TENGs), by coupling triboelectrification and electrostatic induction effects, were usually designed with single-electrode [7][8][9][10][11] or interdigitated electrode structures [12][13][14][15] to produce electricity. However, their electric outputs are relatively low because of the inefficient utilization of surface charges on dielectric layers. Recently, a new R-TENG, which converts conventional interfacial effect at solid-liquid interfaces into bulk effect, was proposed to effectively utilize the surface charges, and generate a high-power density up to 50.10 W m −2 , [16] which further greatly promotes the research interests about raindrop energy harvesting. Since that, many efforts have been devoted to further improving the performance of such TENG, [17,18] revealing its working mechanism, [19][20][21] and realizing different application scenarios. [22][23][24][25][26][27][28][29] Specifically, the complementary harvesting of raindrop and solar energies provides more efficient, reliable and sustainable energy supply, which has aroused wide interests from different research communities. [30][31][32] Nevertheless, the practical application of R-TENGs still faces huge challenges, due to the irregular distributions in the raindrop volume, frequency,The triboelectric nanogenerator (TENG) is regarded as an effective strategy for harvesting energy from raindrops, and is a complementary solution with solar cells to achieve all-weather energy harvesting and sustainable energy supply. However, due to the irregularity of natural rainfalls in the volume, frequency, density, and location, designing high-efficiency raindrop TENG (R-TENG) arrays faces great challenges. In this work, a highly transparent, large-area, and high-efficiency R-TENG array with rational material choice, electrode s...