2012
DOI: 10.1063/1.3699218
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Double layer capacitance measured by organic field effect transistor operated in water

Abstract: Pentacene ultra thin film transistors were exposed to water and operated with a conventional silicon/silicon oxide bottom gate and an electrolyte top gate controlled by a working electrode. The transistors are highly sensible (mu V) to the electrochemical potential of the aqueous electrolyte. We show that dual gate operation permits the measurement of the double layer capacitance, C-DL = 14.6 mu F/cm(2). The device exhibits a fast (4.6 ms) and stable response, without bias stress as opposed to conventional bot… Show more

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Cited by 74 publications
(81 citation statements)
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“…This layer accounts for the very high-gate capacitance, which is in the order of mF cm À 2 (ref. 38). The hysteresis is less pronounced in a higher ionic solution ( Fig.…”
Section: Resultsmentioning
confidence: 99%
“…This layer accounts for the very high-gate capacitance, which is in the order of mF cm À 2 (ref. 38). The hysteresis is less pronounced in a higher ionic solution ( Fig.…”
Section: Resultsmentioning
confidence: 99%
“…Schließlich bilden sich Ladungsdoppelschichten (CDLs,"charge double layers") an der Gate-Elektrolyt-Grenzfläche und der Elektrolyt-HalbleiterGrenzfläche,d ie in Abbildung 6a mit C CDL-1 bzw.C CDL-2 bezeichnet sind und Kapazitäten bis zu 14.6 mFcm À2 in 0.1m Kochsalzlçsung aufweisen. [66] Kapazitätswerte bis zu einigen hundert mFcm À2 kçnnen mit ionischen Flüssigkeiten und polymeren Elektrolyten wegen der viel hçheren Ionenkonzentrationen erzielt werden. [67] Die beiden CDL-Kondensatoren in Reihe,d ie in Abbildung 6a angegeben sind, bilden das EG-TFT-Ansteuerungssystem, da die Kapazitätskopp-lung zwischen den CDLs und dem Halbleiter einen zweidimensionalen (2D) Kanal freier Ladungen im Halbleiter erzeugt.…”
Section: Druckbare Bioelektronische Elektrolytgesteuerte Dünnschichttunclassified
“…Similarly to OECT technology, electrolyte-gated organic field-effect transistors (EGOFETs)-also known as water-gated OFETs-are worth mentioning. EGOFETs can operate either with pure water or saline solutions as gate medium and they can be fabricated using many different semiconductors (both p-and n-type) [47,[131][132][133]. Such transistors are characterized by currents that are much smaller than the OECT counterpart [134,135].…”
Section: Organic Field-effect Transistorsmentioning
confidence: 99%