“…11,12,[22][23][24][25][26][27] MgO (lattice constant 0.4212 nm), which has a rock salt crystal structure, is a widely used substrate for epitaxy of magnetite (lattice constant 0.83987 nm) due to the small lattice mismatch of only 0.33%. 9 Antiphase boundaries (APB) are structural defects occurring in thin films during epitaxial growth and are observed in Fe 3 O 4 films when grown on a variety of substrates like MgO, MgAl 2 O 4 , and α-Al 2 O 3 . 11,12,[28][29][30] Since the Fe 3 O 4 (Fd3m) crystal structure is of lower symmetry than MgO (Fm3m), there are several equivalent nucleation sites on the MgO (100) surface, which enforce the formation of APBs at the interface of the neighboring grains.…”