“…Recently, several Gd silicides (e.g., GdSi, Gd 5 Si 4 Gd 5 Si 3 , and GdSi 5 ) have been reported to exhibit exotic magnetic properties [40][41][42][43][44], due to the exchange interaction between localized 4f electrons, which is mainly mediated by conduction electrons. In particular, the magnetocaloric material Gd 5 Si 4 shows magnetic ordering at 70 • C and has a high magnetic moment of eff = 9.6 B [41][42][43].…”