Disproportionation and recombintion of cyclopentyl radicals

Tilquin, Bernard; Allaert, J.; Claes, P.

doi:10.1021/j100597a032

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1976

1989

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Cited by 6 publications

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“…Each of these reactions can be thought of as yet another manifestation of the electrolyte property of zeolites. 2 The reduction of Ni2+ by NO is slow at room temperature but proceeds rapidly at 100 °C. The reduction of Cu2+ by NO occurs instantaneously at room temperature.…”

Section: Discussionmentioning

confidence: 99%

Low temperature disproportionation and combination reactions of cycloalkyl radicals in the solid state

Tilquin¹,

Allaert²,

Claes³

1978

J. Phys. Chem.

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In ref 11 the width of the shoulder Is suggested to extend as large as 1400 G. In this case the result of the analytical fit gives the experimental hyperfine coupling constants as Aj_ = 14.25 G and Aii = 100 G (±50 G), and for the Interpretation of the experimental result either model will do, with or without the 1 s-like cavity center In the As4S6 casket. (39) There Is no decisive evidence to determine which model is convincing,

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Section: Discussionmentioning

confidence: 99%

Low temperature disproportionation and combination reactions of cycloalkyl radicals in the solid state

Tilquin¹,

Allaert²,

Claes³

1978

J. Phys. Chem.

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A Radical Post‐Scavenging Study of Irradiated Cyclic Hydrocarbons in the Solid State

Tilquin

Allaert

Claes

1977

Bulletin des Soc Chimique

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Cycloalkanes were irradiated in the solid phase at 77 K. Post‐irradiation scavenging of radicals by dissolving the irradiated cycloalkane at low temperature (100 ‐ 165 K) in a propane‐oxygen mixture lowers the dicycloalkyl and cycloalkene G values to an extent of 35‐55%. From the Δ G decrease values, we propose that the trapped radical G values be 3.1, 2.7 and 2.7 at 77 K for cyclopentyl, cyclohexyl and cycloheptyl radicals, respectively.

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Etude de la radiolyse du pentane normal a 77 K par capture des radicaux apres l'irradiation

Allaert

Claes

Tilquin

1976

International Journal for Radiation Physics and Chemistry

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Disproportionation and recombintion of cyclopentyl radicals

Cited by 6 publications

References 0 publications

Low temperature disproportionation and combination reactions of cycloalkyl radicals in the solid state

Low temperature disproportionation and combination reactions of cycloalkyl radicals in the solid state

A Radical Post‐Scavenging Study of Irradiated Cyclic Hydrocarbons in the Solid State

Etude de la radiolyse du pentane normal a 77 K par capture des radicaux apres l'irradiation

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