Abstract. Texture, plastic deformation, and phase transformation
mechanisms in perovskite and post-perovskite are of general interest for our
understanding of the Earth's mantle. Here, the perovskite analogue
NaCoF3 is deformed in a resistive-heated diamond anvil cell (DAC) up to 30 GPa and 1013 K. The in situ state of the
sample, including crystal structure, stress, and texture, is
monitored using X-ray diffraction. A phase transformation from a perovskite
to a post-perovskite structure is observed between
20.1 and 26.1 GPa. Normalized stress drops by a factor of 3 during
transformation as a result of transient weakening during the transformation.
The perovskite phase initially develops a texture with a maximum at 100 and
a strong 010 minimum in the inverse pole figure of the compression
direction. Additionally, a secondary weaker 001 maximum is observed later
during compression. Texture simulations indicate that the initial deformation of
perovskite requires slip along (100) planes with significant contributions
of {110} twins. Following the phase transition
to post-perovskite, we observe a 010 maximum, which
later evolves with compression. The transformation follows orientation
relationships previously suggested where the c axis is preserved between
phases and hh0 vectors in reciprocal space of post-perovskite are parallel to
[010] in perovskite, which indicates a martensitic-like transition
mechanism. A comparison between past experiments on bridgmanite and current
results indicates that NaCoF3 is a good analogue to understand the
development of microstructures within the Earth's mantle.