“…The surface scattering (or specular) component represents the surface-scattered Fresnel radiation, which results in emission minima at the very strong molecular vibration bands Conel, 1969;Hunt and Logan, 1972;Salisbury et al, 1987;Salisbury and Wald, 1992). A strong band minimum in emission (and therefore a strong peak in reflectance from Kirchhoff's law, E = 1 À R, where E is emissivity and R is reflectance (Nicodemus, 1965)) is produced by Fresnel reflection from surface scattering because high opacity and strong absorption coefficients within the wavelength band produce a mirror-like characteristic and essentially little incident radiance is transmitted or absorbed and the majority is reflected (e.g., Hunt and Vincent, 1968;Conel, 1969;Hunt and Logan, 1972;Salisbury et al, 1987;Salisbury and Wald, 1992). These emission minima are referred to as 'reststrahlen bands' and emission at these bands is due to 'first surface reflection' or 'surface scattering' because all returned radiation has been reflected from the surface of the material and none has passed through the material (Gaffey et al, 1993).…”