2006
DOI: 10.1021/es060087+
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Direct Volatilization of Naphthalene to the Atmosphere at a Phytoremediation Site

Abstract: Phytoremediation systems are known to reduce groundwater contamination by at least three major mechanisms: plant uptake, phytovolatilization, and enhanced rhizosphere bioremediation. The potential for such systems to enhance a fourth remediation pathway--direct surface volatilization of contaminants through the subsurface and into the atmosphere-has not yet been investigated in the field. A vertical flux chamber was used to measure direct surface volatilization of naphthalene over nine months at a creosote-con… Show more

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Cited by 28 publications
(16 citation statements)
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References 39 publications
(65 reference statements)
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“…Over the last decade, phytoremediation of contaminated soils, sediments, and ground water has emerged as an ecologically and economically sound cleanup technology and gained widespread public acceptance (Dietz and Schnoor, 2001; Olson et al, 2003; Parrish et al, 2005; Pilon‐Smits, 2005). Vegetation can affect the fate of soil contaminants in several ways, including sorption to roots, enhanced direct volatilization (Marr et al, 2006), and uptake into the plant. One aspect of phytoremediation involves the biodegradation of organic compounds in the plant rhizosphere, the zone around the plant roots.…”
mentioning
confidence: 99%
“…Over the last decade, phytoremediation of contaminated soils, sediments, and ground water has emerged as an ecologically and economically sound cleanup technology and gained widespread public acceptance (Dietz and Schnoor, 2001; Olson et al, 2003; Parrish et al, 2005; Pilon‐Smits, 2005). Vegetation can affect the fate of soil contaminants in several ways, including sorption to roots, enhanced direct volatilization (Marr et al, 2006), and uptake into the plant. One aspect of phytoremediation involves the biodegradation of organic compounds in the plant rhizosphere, the zone around the plant roots.…”
mentioning
confidence: 99%
“…C 3 -dibenzothiophenes vs. C 3 -chrysenes (D 3 /C 3 ) ratios can be used to detect later stages of weathering for diesel and crude oils (Douglas et al, 1996). Biodegradation is often the primary mechanism for PAH weathering, but volatilization and leaching may also weather the lighter PAHs as plants physically disturb the petroleum distillate matrix Marr et al, 2006). We did not observe more weathered D3/C3 ratios for any vegetated sediment fractions relative to the non-vegetated sediment fractions.…”
Section: Pah Weathering and Sediment Compositionmentioning
confidence: 73%
“…13.7). Marr et al (2006) studied the relation of the phytoremediation plot at Oneida to the volatilization of naphthalene as a loss mechanism from the contaminated aquifer. Similar decreases were observed in the ratio of naphthalene concentration to total PAH (as TPAH) concentration with depth ( Fig.…”
Section: Plant Interaction and Uptake Pathwaysmentioning
confidence: 99%