2008
DOI: 10.1063/1.2995988
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Direct measurements of the energy flux due to chemical reactions at the surface of a silicon sample interacting with a SF6 plasma

Abstract: Energy exchanges due to chemical reactions between a silicon surface and a SF 6 plasma were directly measured using a heat flux microsensor. The energy flux evolution was compared with those obtained when only few reactions occur at the surface to show the part of chemical reactions. At 800 W, the measured energy flux due to chemical reactions is estimated at about 7 W.cm -2 against 0.4 W.cm -2 for ion bombardment and other contributions. Time evolution of the HFM signal is also studied. The molar enthalpy of … Show more

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Cited by 23 publications
(20 citation statements)
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“…The reaction enthalpy was estimated by using the expression (13). We found a rather good agreement between our evaluation (−2200 kJ.mol -1 ) and the theoretic value (-1931 kJ.mol -1 ) [26].…”
Section: Energy Flux In a Sf 6 Plasma Interacting With Siliconsupporting
confidence: 64%
See 1 more Smart Citation
“…The reaction enthalpy was estimated by using the expression (13). We found a rather good agreement between our evaluation (−2200 kJ.mol -1 ) and the theoretic value (-1931 kJ.mol -1 ) [26].…”
Section: Energy Flux In a Sf 6 Plasma Interacting With Siliconsupporting
confidence: 64%
“…A measurement of the energy transfer due to these reactions was carried out by placing a silicon sample on the HFM and by submitting it to a SF 6 inductively coupled plasma (figure 12) [26] . figure 13(a), we show the results we have obtained by alternating Ar plasmas and SF 6 plasmas when a silicon sample was mounted on the HFM.…”
Section: Energy Flux In a Sf 6 Plasma Interacting With Siliconmentioning
confidence: 99%
“…Energy flux to a substrate was measured by many researchers using variety of thermal probes (TPs) in the past in the RF plasma [32][33][34][35][36][37], RF magnetron plasma [38,39], and DC grow discharge plasma [40].…”
Section: Measurement Of Spatial Distribution Of Heat Flux To the Subsmentioning
confidence: 99%
“…Previous works have shown the great interest of performing energy flux measurements with the HFM to study such mechanisms. For example, it has been possible to detect the energy transferred to the surface by a chemical reaction (silicon etching) or by the condensation of atoms (plasma sputtering deposition) [15,17].…”
Section: Introductionmentioning
confidence: 99%
“…[12,14] Another way to determine the energy transfer between plasma and surface is the use of a sensor which is sensitive to the energy flux itself. The Heat Flux Microsensor (HFM) which was firstly explored for plasma diagnostics at GREMI exactly uses this principle [15,16]. The microsensor is composed of a Pt100 temperature sensor and a thermopile.…”
Section: Introductionmentioning
confidence: 99%