DIPEA-induced activation of OH<sup>−</sup> for the synthesis of amides <i>via</i> photocatalysis

Wu, Mei; Huang, Sheng; Hou, Huiqing; Lin, Jie; Ma, Lin; Zhou, Sunying; Zheng, Zhiqiang; Sun, Wei‐Ming; Fang, Ke

doi:10.1039/d2ra02107b

RSC Adv.

2022

DOI: 10.1039/d2ra02107b

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DIPEA-induced activation of OH⁻ for the synthesis of amides via photocatalysis

Mei Wu

Sheng Huang

Huiqing Hou

et al.

Abstract: Under weak organic base condition DIPEA as a reductant to increase the nucleophilicity of H2O an excellent potential system for nitrile degradation.

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Radical‐Induced C−H Direct Activation of Quinoxaline via Visible Light Photoredox‐Catalyzed

Tan,

Wu,

Kang

et al. 2023

Asian J Org Chem

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The photocatalytic C(sp2)‐H functionalization of quinoxaline derivatives using potassium iodide as photoredox‐mediators has been described. The lower price of potassium iodide compared to standard photocatalysts, readily available substrates, and environmental solvent constitute make this method cost‐effective and interesting. A catalytic amount of KI is applied to the direct activation of C‐H bonds for the construction of heterocyclic compound. This system has simple operation, the characteristics of easy to obtain raw materials, high yield and excellent substrate adaptability provide a new method for the synthesis of C2 substituent quinoxalines.

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Radical‐Induced C−H Direct Activation of Quinoxaline via Visible Light Photoredox‐Catalyzed

Tan,

Wu,

Kang

et al. 2023

Asian J Org Chem

Self Cite

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DIPEA-induced activation of OH⁻ for the synthesis of amides via photocatalysis

Abstract: Under weak organic base condition DIPEA as a reductant to increase the nucleophilicity of H2O an excellent potential system for nitrile degradation.

Cited by 1 publication

References 43 publications

Radical‐Induced C−H Direct Activation of Quinoxaline via Visible Light Photoredox‐Catalyzed

Radical‐Induced C−H Direct Activation of Quinoxaline via Visible Light Photoredox‐Catalyzed

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DIPEA-induced activation of OH− for the synthesis of amides via photocatalysis

Abstract: Under weak organic base condition DIPEA as a reductant to increase the nucleophilicity of H2O an excellent potential system for nitrile degradation.

Cited by 1 publication

References 43 publications

Radical‐Induced C−H Direct Activation of Quinoxaline via Visible Light Photoredox‐Catalyzed

Radical‐Induced C−H Direct Activation of Quinoxaline via Visible Light Photoredox‐Catalyzed

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DIPEA-induced activation of OH⁻ for the synthesis of amides via photocatalysis