Dimethylgold(III) complexes of α-amino acids and related ligands

Tobias, R. Stuart; Rice, Catherine E.; Beck, Wolfgang; Purucker, Bernhard; Bartel, Klaus

doi:10.1016/s0020-1693(00)93410-8

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H 1 -Alkyl H 2 -Olefin and H 3 -Allyl Complexes1

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Cited by 14 publications

(1 citation statement)

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“…Monomeric, lightsensitive dimethylgold(iii) complexes (32) are obtained by the reaction of [(H 3 C) 2 Au(OH 2 )]NO 3 with a-amino acid salts. [26] With the exception of [(H 3 C) 2 Au(CysO)], N,O-chelates are observed. An S,O-chelate structure has been proposed for [(H 3 C) 2 Au(CysO)].…”

Section: H 1 -Alkyl H 2 -Olefin and H 3 -Allyl Complexesmentioning

confidence: 99%

Bioorganometallic Chemistry - Transition Metal Complexes withα-Amino Acids and Peptides

Severin¹,

Bergs²,

Beck³

1998

Angewandte Chemie International Edition

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346

153

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A new, interdisciplinary research area has emerged known as bioorganometallic chemistry. It focuses on the introduction of organometallic fragments into biomolecules (see, for example, structure on the right). "Classical" α-amino acid and peptide ligands have proven particularly versatile, and provide access to compounds that display interesting stereochemistry. α-Amino acids and peptides can be synthesized, labeled, stabilized, or activated by organometallic fragments.

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Section: H 1 -Alkyl H 2 -Olefin and H 3 -Allyl Complexesmentioning

confidence: 99%

Bioorganometallic Chemistry - Transition Metal Complexes withα-Amino Acids and Peptides

Severin¹,

Bergs²,

Beck³

1998

Angewandte Chemie International Edition

Self Cite

346

153

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Biometallorganische Chemie – Übergangsmetallkomplexe mit α-Aminosäuren und Peptiden

Severin¹,

Bergs²,

Beck³

1998

Angewandte Chemie

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105

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Ein neues interdisziplinäres Forschungsgebiet ist die Biometallorganische Chemie; sie befaßt sich mit der Einführung von metallorganischen Fragmenten in Biomoleküle (siehe z. B. Struktur rechts). Die „klassischen”︁ α‐Aminosäure‐ und Peptidliganden haben sich dabei als besonders vielseitig erwiesen und eröffnen unter anderem einen Zugang zu stereochemisch interessanten Verbindungen. α‐Aminosäuren und Peptide können durch metallorganische Verbindungen synthetisiert, markiert, stabilisiert oder aktiviert werden.

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From Organic Nitrogen Anions by Ligand Substitution Reactions with Complexes of the Metals

Kargol¹,

Albanese²,

Burmeister³

1995

Inorganic Reactions and Methods

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Dimethylgold(III) complexes of α-amino acids and related ligands

Cited by 14 publications

References 19 publications

Bioorganometallic Chemistry - Transition Metal Complexes withα-Amino Acids and Peptides

Bioorganometallic Chemistry - Transition Metal Complexes withα-Amino Acids and Peptides

Biometallorganische Chemie – Übergangsmetallkomplexe mit α-Aminosäuren und Peptiden

From Organic Nitrogen Anions by Ligand Substitution Reactions with Complexes of the Metals

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