Dimethylammonium Pentachlorobismuthate(III)

Crystal structure, computational study, optical and vibrational properties of a new luminescent material based on bismuth(III): (C10H28N4)[Bi2Cl10]

“…The projection of the atomic arrangement of the compound reveals that these isolated dimeric anions are located in the middle edges of the cell belonging to the plan x=0 to form a (0D) network (Figure 2 (a, b)). This anion architecture is similar to those found in the literature [49][50][51][52]. Anions (in green) and cations (in blue) are coloured by symmetry equivalence for the clarity of the structure arrangement (Figure 2 (b,c)).…”

Chloridobis(1,10-phenanthroline)zinc(II) tetrachlorido(1,10-phenanthroline)bismuthate(III) monohydrate

“…In this BiN 2 Cl 4 octahedron, the Bi1-N1 = 2.505 (3) Å, Bi1-N2 = 2.474 (3) Å, Bi1-Cl1 = 2.7272 (10) Å, Bi1-Cl2 = 2.6708 (10) Å, Bi1-Cl3 = 2.7841 (12) Å, Bi1-Cl4 = 2.5853 (11) Å. All bond lengths are within commonly accepted values in the literature (James et al, 2000;Jarraya et al, 1995). The crystal structure of the [Bi(phen)I 4 ]salt has already been determined (Bowmaker et al, 1998), and the Bi atom therein is coordinated in a similar distorted octahedron by two N atoms and four I atoms.…”

“…For related bismuth compounds, see: James et al (2000); Jarraya et al (1995); Bowmaker et al (1998). For a related [Zn(phen) 2 Cl] + coordinated cation structure, see: Yu & Zhang (2006).…”