“…During the past decades, a large number of supramolecular structures have been assembled and characterized due to their interesting structure and many respected applications in sensors, catalysis, optical/optoelectronic and magnetic materials etc. [7][8][9][10][11][12][13] . Here, we report the solvothermal synthesis and crystal structure of a supramolecular compound [ClP(NHt-Bu) 3 ](Cl) (1).…”