1968
DOI: 10.1002/cber.19681010113
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„Dimere des 1.2‐Dimethyl‐cyclobutadiens”︁

Abstract: Dimethylen-cyclobuten (1) addiert Chlorwasserstoff zu drei isomeren Dichlor-diniethyl-cyclobutenen (3a-c).

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Cited by 30 publications
(14 citation statements)
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“…In this paper we conclude our study of this sulfone system with a report on the preparation of cis-trans mixtures of two (4,9) symmetrically and five (5)(6)(7)(8)10) unsymmetrically substituted l,3-diphenyl-l,3-dihydrothieno [3,[4][5] [quinoxaline 2,2-dioxides and their response to similar oxidative and reductive methods of S02 extrusion.…”
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confidence: 80%
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“…In this paper we conclude our study of this sulfone system with a report on the preparation of cis-trans mixtures of two (4,9) symmetrically and five (5)(6)(7)(8)10) unsymmetrically substituted l,3-diphenyl-l,3-dihydrothieno [3,[4][5] [quinoxaline 2,2-dioxides and their response to similar oxidative and reductive methods of S02 extrusion.…”
mentioning
confidence: 80%
“…The extrusion of S02 from cis-trans mixtures of 5,8-dimethyl- (4), 5-methyl-(5), 5-methoxy-(6), 5-nitro- (7), 5-amino-(8), 1,3,5,8-tetramethyl-(9), and 1,5-(10a) and l,8-dimethyl-l,3-diphenyl-l,3-dihydrothieno [3,[4][5][6]quinoxaline 2,2-dioxide (10b) by oxidative (alkaline hydrogen peroxide, oxygen, and peracetic acid) and reductive methods (Raney nickel and sodium borohydride) is reported. Thus, alkaline hydrogen peroxide oxidation of 4, 5, and 6 afforded, respectively, 2-benzoyI-3-benzyl-5,8-dimethylquinoxaIme ( 13) and separable mixtures of 2-benzoyl-3-benzyl-( 14) and 3-benzoyl-2-benzyl-5-methylquinoxaline (15) and 2-benzoyl-3-benzyl-( 16) and 3-benzoyl-2-benzyl-5-methoxyquinoxaline (17).…”
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confidence: 99%
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“…Äther gewonnen 11 . Neuere Untersuchungen zeigten, daß die Isomerenverteilung durch die Einleitungsgeschwindigkeit des Chlorwasserstoffs beeinflußt werden kann: schnelles Einleiten läßt bevorzugt das Isomere 1 a entstehen, während bei sehr langsamem Einleiten vergleichbare Mengen der Isomeren erhalten werden.…”
Section: Experimenteller Teilunclassified