“…In general, all bond distances and angles are within the values characteristic according the atom involved, the bond distances selected are P1-O1 1.4831(10), P1-N3 1.6340(12), P1-N2 C1-N1-P1 128.30(11), C9-N2-C10 116.17(11), C9-N2-P1 119.16(10), C10-N2-P1 116.69(9), C17-N3-C18 114.66(11), C17-N3-P1 123.61(10), C18-N3-P1 119.56(9), O2-C1-N1 126.11(13), O2-C1-C2 120.73(12), F1-C3-C4 118.20(13) and F1-C3-C2 120.21(13)°.In the phosphoric triamide structure reported here, the P═O and N-H groups are syn with respect to each other and in the crystal packing, pairs of N-H…O═P hydrogen bonds form centrosymmetric dimers (N…O = 2.7329(16) Å,Table 2). Moreover, the phosphoryl group isinvolved in a P═O…π interaction [O…Cg = 3.507 Å, Cg is the centroid of C 6 F 5 ring], Figure 2.…”