Dielectric study of allyl chloride with 2-butanol in microwave frequency range

Maharolkar, Aruna P.; Sudake, Y. S.; Kamble, S. P.; Murugkar, A. G.; Patil, S. S.; Khirade, P. W.

doi:10.1063/1.4810634

Cited by 7 publications

(4 citation statements)

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“…Figure 1 shows negative deviation of excess molar volume in MEK+NB mixtures illustrates the structural contribution, of constituents occurring by appropriate geometrical fitting in this case, i.e. better interstitial spacing of solute and solvent in the system [4][5][6][7]. The molecules of MEK assist with nitrobenzene are confirmed from our study.…”

Section: Discussionsupporting

confidence: 62%

“…Bruggeman factor. Bruggeman's formula [4] can be employed as the important proof of presence intermolecular interactions in binary mixtures. The total volume of the solute-solvent interactions and is important shown by the deviation in linearity of the Bruggeman factor.…”

Section: Discussionmentioning

confidence: 99%

“…Preference of ideal solvent for given solute is versatile problem in front of various types of industries like ceramics, pharmaceuticals and research and development [4][5][6][7][8]. Benzene group acts as good solvent for ketone group.…”

Section: Introductionmentioning

confidence: 99%

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Microwave dielectric relaxation & polarization study of binary mixture of methylethylketone with nitrobenzene

Maharolkar¹,

Murugkar²,

Khirade³

et al. 2019

Bull. Chem. Soc. Eth.

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Present paper reveals detailed study of dielectric relaxation and dielectric polarization and physicochemical study of binary polar-polar liquid mixture i.e. dielectric constant, relaxation time, viscosity, density of methylethylketone (MEK) with nitrobenzene (NB) at 303 K. The measured dielectric and physicochemical parameters employed to acquire additional derived properties like Bruggeman factor, molar refraction and excess properties like static dielectric constant, excess inverse relaxation time, excess molar volume, excess viscosity, excess molar refraction, Gibbs free energy, and enthalpy of activation. The variation of this parameters with composition of these quantities has been used to explain the type, strength and nature of intermolecular interactions between MEK+NB binary mixture. Attained results authenticate that there are strong hydrogen-bond interactions between unlike molecules of different groups of MEK+NB mixtures and that 1:1 complexes are produced and strength of intermolecular interaction rises with rise in concentration of MEK.

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Section: Discussionsupporting

confidence: 62%

Section: Discussionmentioning

confidence: 99%

See 1 more Smart Citation

Microwave dielectric relaxation & polarization study of binary mixture of methylethylketone with nitrobenzene

Maharolkar¹,

Murugkar²,

Khirade³

et al. 2019

Bull. Chem. Soc. Eth.

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“…Earlier few researchers reported dielectric properties of ALC with n-butanol 4 and alcohols. 5 The dielectric properties of some ketones are reported by Buta Singh, 6 Crossely 7 and Madhurima.…”

Section: Introductionmentioning

confidence: 99%

Dielectric Study of Allyl Chloride with 2-Pentanone and 2-Hexanone in Microwave Frequency Range

Sudake¹,

Kamble²,

Maharolkar³

et al. 2012

Bulletin of the Korean Chemical Society

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Dielectric measurement on binary mixtures of Allyl chloride (ALC) with 2-Pentanone (2-PE) and 2-Hexanone (2-HE) has been carried out over the entire concentration range using Time Domain Reflectometry (TDR) technique at various temperatures in microwave frequency range of 10 MHz to 10 GHz. The static dielectric constant, excess static dielectric constant ( ), effective Kirkwood correlation factor (g eff ) of binary mixtures over entire concentration range were determined to study the effect of increasing alkyl group of ketones on hetero molecular interaction. It was found that magnitude of excess static dielectric constant of mixtures increases with increase of alky group of ketones. The study reveals that the dipole moment of Allyl chloride in mixture have antiparallelism tendency where as 2-pentanone and 2-hexanone have parallelism tendency. Excess static dielectric constant is also fitted to Redlich-Kister equation to get information about rates of multimers formation.

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