2015
DOI: 10.1039/c4ra13950j
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Dielectric properties of Co(CO3)(H2O)2(C3H4N2)2 and [Co(C3H3N2)2]n

Abstract: Dielectric relaxation phenomenon with non-Debye dynamics in Co(CO3)(H2O)2(C3H4N2)2 and [Co(C3H3N2)2]n, resembling the behaviour of ferroelectric relaxors is presumably connected with the charge carriers.

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Cited by 2 publications
(1 citation statement)
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“…In this conduction type, the large-polaron wells at two sites are assumed to overlap, thus reducing the polaron hopping energy, which is given by: W H = W H0 (1 − r p / R ) where W H0 is associated with the activation energy, r p is the radius of a large polaron and R is the inter-site separation. The relation between the power parameter s and temperature for the OLPT mechanism is as follows: 60 where α is the spatial extent of the polaron, R ω is the hopping length at the angular frequency ω , k is the Boltzmann constant and T is the temperature. The higher values of activation energy in our case also support this argument.…”
Section: Resultsmentioning
confidence: 99%
“…In this conduction type, the large-polaron wells at two sites are assumed to overlap, thus reducing the polaron hopping energy, which is given by: W H = W H0 (1 − r p / R ) where W H0 is associated with the activation energy, r p is the radius of a large polaron and R is the inter-site separation. The relation between the power parameter s and temperature for the OLPT mechanism is as follows: 60 where α is the spatial extent of the polaron, R ω is the hopping length at the angular frequency ω , k is the Boltzmann constant and T is the temperature. The higher values of activation energy in our case also support this argument.…”
Section: Resultsmentioning
confidence: 99%