Dielectric and Piezoelectric Properties of Niobium-modified BiInO3–PbTiO3 Perovskite Ceramics with High Curie Temperatures

Zhang, Shujun; Xia, Ru; Randall, Clive A.; Shrout, Thomas R.; Duan, Runrun; Speyer, Robert F.

doi:10.1557/jmr.2005.0254

Cited by 83 publications

(45 citation statements)

References 14 publications

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“…[1][2][3] The operating temperature of piezoelectric ceramics is generally limited to one-half of the Curie point ͑T C ͒ due to loss of polarization, typically at temperatures lower than 200°C ͓e.g., 150°C for the conventional piezoelectric materials based on the Pb͑Zr 1−x Ti x ͒O 3 ͑PZT͔͒ with a Curie temperature, T C = 386°C. 4 After excellent piezoelectric properties for ͑1 − x͒BiScO 3 -xPbTiO 3 ͑BS-PT͒ near the morphotropic phase boundary ͑MPB͒ ͑x = 0.64͒ were reported ͑piezoelectric coefficient, d 33 = 460 pC/ N, planar coupling coefficient, k p = 0.56, and T C = 450°C͒ recently, 5,6 the discovery of several promising high temperature piezoelectric materials with high performance followed in the general BiMeO 3 -PbTiO 3 system, [5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23][24] where Me can be a single cation of valency +3 ͑e.g., Sc 3+ and Fe 3+ ͒ or a mixture of cations with an average valence of +3 ͑e.g., Mg 1/2 Ti 1/2 and Ni 2/3 Nb 1/3 ͒. It has been proposed that the Bi substitution plays an unusual role of considerable enhancement of both Curie temperature ͑T C ͒ and tetragonality ͑c / a͒, which results from a strong coupling between Pb/Bi cations and B-site cations of strong ferroelectric activity, such as Ti, Zn, and Fe.…”

Section: Introductionmentioning

confidence: 99%

“…Hence, most recent studies have been focusing on nonscandium perovskites. [12][13][14][15][16][17][18][19][20][21][22][23][24] In fact, possible new compositions in BiMeO 3 -PbTiO 3 -based systems are plenty, because B-site Me of BiMeO 3 could be any combination, which gives an average valence of +3. According to the currently available literature, however, the design of BiMeO 3 -PbTiO 3 piezoelectrics faces a significant challenge in that only few systems form a MPB with PbTiO 3 .…”

Section: Introductionmentioning

confidence: 99%

“…This has been demonstrated in such systems as Bi͑Zn 1/2 Ti 1/2 ͒O 3 -PbTiO 3 ͑BZT-PT͒ and Bi͑Zn 2/3 Nb 1/3 ͒O 3 -PbTiO 3 . 7,[20][21][22][23][24] Table I lists the piezoelectric and related properties of BiMeO 3 -PbTiO 3 piezoceramics available in literature. It should be noted that most BiMeO 3 -PbTiO 3 compositions have a relatively high T C .…”

Section: Introductionmentioning

confidence: 99%

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Temperature dependence of piezoelectric properties of high-TC Bi(Mg1/2Ti1/2)O3–PbTiO3

Chen¹,

Tan²,

Jo³

et al. 2009

Journal of Applied Physics

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The temperature dependence of both polarization and electric-field induced strain was investigated for (1−x)Bi(Mg1/2Ti1/2)O3–xPbTiO3 (x=0.36, 0.37, and 0.38), with the morphotropic phase boundary located at x=0.37. Remanent polarization (Pr) and maximum polarization (Pmax) of all compositions are enhanced with increasing temperature up to 175 °C, which is rationalized as improved domain switching due to reduced tetragonality (c/a). The hysteresis during unipolar electric cycling tends to decrease with increase in the fraction of tetragonal phase. Temperature dependent x-ray diffraction demonstrates that switched non-180° domains are stable against thermal depoling above 200 °C, which indicates that the currently investigated materials are suitable for high temperature applications. This promising high-TC piezoelectric is further discussed with reference to oxygen octahedron of the tilted R3c and untilted R3m space groups and the tolerance factor (t).

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Temperature dependence of piezoelectric properties of high-TC Bi(Mg1/2Ti1/2)O3–PbTiO3

Chen¹,

Tan²,

Jo³

et al. 2009

Journal of Applied Physics

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“…PNRs exist over nanometer-length scales in random directions, as a result the average lattice appears different to the local structure, ergo, the spatial coherence length is not significant enough to observe these features using CuK 1 laboratory x-rays. have resulted in sustained or enhanced tetragonality [29][30][31][32]. This behavior is a manifestation of the strong coupling between Pb/Bi and ferroelectrically active displacive B-site cations such as Ti and Fe.…”

Section: Methodsmentioning

confidence: 99%

Variation of Piezoelectric properties and mechanisms across the relaxor-like/Ferroelectric continuum in BiFeO3– (K0.5Bi0.5)TiO3–PbTiO3 ceramics

Bennett

Shrout

Zhang

et al. 2015

IEEE Trans. Ultrason., Ferroelect., Freq. Contr.

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Abstract(1-x-y)BiFeO 3 -x(K 0.5 Bi 0.5 )TiO 3 -y PbTiO 3 piezoelectric ceramics were investigated across the compositional space and contrasted against the BiFeO 3 -(K 0.5 Bi 0.5 )TiO 3 system, a spectrum of relaxor-like/ferroelectric behavior was observed. Structural and piezoelectric properties were found to be closely related to the PbTiO 3 concentration, below a critical concentration, relaxor-type behavior was observed. The mechanisms governing the piezoelectric behavior were investigated with the use of a number of techniques including structural, electrical and imaging techniques. X-ray diffraction established that long-range crystallographic order was promoted above a critical PbTiO 3 concentration, y > 0.1125. Commensurate with the structural analysis, electric-field induced strain responses showed electrostrictive behavior in the PbTiO 3 -reduced compositions, with increased piezoelectric switching in PbTiO 3 -rich compositions. PUND analysis was used to confirm electric-field induced polarization measurements, elucidating that the addition of PbTiO 3 increased the switchable polarization and long-range ferroelectric ordering. PFM of the BiFeO 3 -(K 0.5 Bi 0.5 )TiO 3 -PbTiO 3 system exhibited typical domain patterns above a critical PbTiO 3 threshold, with no ferroelectric domains observed in the lead-free system in the pseudocubic region. Doping of BiFeO 3 -PbTiO 3 has been unsuccessful in the search for high-temperature materials that offer satisfactory piezoelectric properties, however, this system demonstrates that the partial substitution of alternative end-members can be an efficacious method. The partial substitution of PbTiO 3 into BiFeO 3 -(K 0.5 Bi 0.5 )TiO 3 enables long range crystallographic order, resulting in increased polar order and T C . The search for novel high-temperature piezoelectric ceramics can therefore exploit the accommodating nature of the perovskite family, which allows significant variance in chemical and physical character in the exploration of new solid-solutions.

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“…13 It was expected that the Bi(Me)O 3 -PbTiO 3 compositions with higher T c > 300 C will shed light on the potentiality of achieving high temperature stability. [21][22][23][24][25][26] However, except BiScO 3 -PbTiO 3 (BS-PT), 21 the piezoelectric coefficients of the reported Bi(Me)O 3 -PbTiO 3 based ceramics, such as BiFeO 3 -PbTiO 3 (BF-PT), 22 BiInO 3 -PbTiO 3 (BI-PT), 23 Bi(Ni 1/2 Ti 1/2 )O 3 -PbTiO 3 (BNT-PT), 24 Bi(Mg 1/2 Ti 1/2 )O 3 -PbTiO 3 (BMT-PT), 25,26 etc., were lower than 300 pC/N at their respective MPBs. Furthermore, it was reported that piezoelectric coefficients exhibited different degree of degradation in binary and ternary systems, not necessarily associated with their T c /T rt , though higher T c indicating broader usage temperature range.…”

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confidence: 99%

PMN-PT based quaternary piezoceramics with enhanced piezoelectricity and temperature stability

Luo

Zhang

Liu

et al. 2014

Applied Physics Letters

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The phase structure, piezoelectric, dielectric, and ferroelectric properties of (0.80 − x)PMN-0.10PFN-0.10PZ-xPT were investigated systematically. The morphotropic phase boundary (MPB) was confirmed to be 0.30 < x < 0.34. Both MPB compositions of x = 0.32 and x = 0.33 exhibit high piezoelectric coefficients d33 = 640 pC/N and 580 pC/N, electromechanical couplings kp of 0.53 and 0.52, respectively. Of particular importance is that the composition with x = 0.33 was found to process high field-induced piezoelectric strain coefficient d33* of 680 pm/V, exhibiting a minimal temperature-dependent behavior, being less than 8% in the temperature range of 25–165 °C, which can be further confirmed by d31, with a variation of less than 9%. The temperature-insensitive d33* values can be explained by the counterbalance of the ascending dielectric permittivity and descending polarization with increasing temperature. These features make the PMN-PT based quaternary MPB compositions promising for actuator applications demanding high temperature stability.

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Dielectric and Piezoelectric Properties of Niobium-modified BiInO₃–PbTiO₃ Perovskite Ceramics with High Curie Temperatures

Cited by 83 publications

References 14 publications

Temperature dependence of piezoelectric properties of high-TC Bi(Mg1/2Ti1/2)O3–PbTiO3

Temperature dependence of piezoelectric properties of high-TC Bi(Mg1/2Ti1/2)O3–PbTiO3

Variation of Piezoelectric properties and mechanisms across the relaxor-like/Ferroelectric continuum in BiFeO<sub>3</sub>– (K0.5Bi0.5)TiO3–PbTiO3 ceramics

PMN-PT based quaternary piezoceramics with enhanced piezoelectricity and temperature stability

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