2015
DOI: 10.1007/s10854-015-3547-5
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Dielectric and complex impedance analysis of Sr5Nb4TiO17 ceramic with perovskite-like structure

Abstract: Dense Sr 5 Nb 4 TiO 17 ceramic was prepared by a solid state reaction route. XRD and SEM results revealed the formation of single phase with perovskite-like structure and space group Pnnm at room temperature. Three sets of dielectric peaks were observed through dielectric measurement. A phase transition from orthorhombic Pnnm to Immm was obtained at *596°C. The combined Z 00 and M 00 plots confirmed the heterogeneous electrical microstructure of the Sr 5 Nb 4 TiO 17 ceramic.

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Cited by 2 publications
(2 citation statements)
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“…Space charges tend to aggregate at grain boundaries, which leads to electrically heterogeneous microstructures characterized by insulating grains and semiconducting grain boundaries. It is well known that impedance spectroscopy is a favorable technique to separate inhomogeneous microstructures by correlating the electrical properties to the microstructures [42][43][44]. Hence, to get a comprehensive understanding of the thermal activated dielectric anomaly, complex impedance analysis was conducted over the temperature range of 530 to 610 o C (the temperature range where dielectric anomaly occurred).…”
Section: Figurementioning
confidence: 99%
“…Space charges tend to aggregate at grain boundaries, which leads to electrically heterogeneous microstructures characterized by insulating grains and semiconducting grain boundaries. It is well known that impedance spectroscopy is a favorable technique to separate inhomogeneous microstructures by correlating the electrical properties to the microstructures [42][43][44]. Hence, to get a comprehensive understanding of the thermal activated dielectric anomaly, complex impedance analysis was conducted over the temperature range of 530 to 610 o C (the temperature range where dielectric anomaly occurred).…”
Section: Figurementioning
confidence: 99%
“…These compounds consist of five corner shared octahedral slabs connected with each other. The crystal structure and dielectric properties of layered perovskites has received great attention in the last few years [13]. For example, Zinc-substituted Ca0.2La0.8TiO3.4 possesses εr = 57.6, Q×f = 17,100 GHz, τf = -4.9 ppm/°C [14].…”
Section: Introductionmentioning
confidence: 99%