1994
DOI: 10.1515/znb-1994-0310
|View full text |Cite
|
Sign up to set email alerts
|

Die Kristallstruktur von Gadolinium-(III)-hydrogensulfat Gd(H SO4)3 / Crystal Structure of Gadolinium-(III)-hydrogensulfate Gd(HSO4)3

Abstract: Gd(HSO4)3 is obtained on treatment of Gd2(SO4)3 in conc. H2SO4 in closed vessels at 200 °C. The extremely moisture-sensitive crystals belong to the orthorhombic space group Pbca. Lattice constants are a = 12.080(8), b = 9.574(8), c = 16.513(8)Å and Z = 8. Gadolinium is coordinated by eight oxygen atoms of the hydrogensulfate ligands forming a distorted square antiprism. There are three different HSO4- anions within the structure. One of them is coordinated with two Gd atom s while two HSO4- anions bridge three… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

0
7
0
2

Year Published

1994
1994
2017
2017

Publication Types

Select...
6

Relationship

0
6

Authors

Journals

citations
Cited by 9 publications
(9 citation statements)
references
References 0 publications
0
7
0
2
Order By: Relevance
“…Ein Vergleich der vorgestellten Kristallstrukturen mit jenen der bisher charakterisierten Selten-Erd-Hydrogensulfate von Erbium [1] und Gadolinium [2] zeigt die erwartete Zunahme der Koordinationszahl von M 3+ . In den hier vorgestellten Hydrogensulfaten treten nur sehr schwache ¹Wasserstoffbru È ckenbindungenª auf.…”
unclassified
“…Ein Vergleich der vorgestellten Kristallstrukturen mit jenen der bisher charakterisierten Selten-Erd-Hydrogensulfate von Erbium [1] und Gadolinium [2] zeigt die erwartete Zunahme der Koordinationszahl von M 3+ . In den hier vorgestellten Hydrogensulfaten treten nur sehr schwache ¹Wasserstoffbru È ckenbindungenª auf.…”
unclassified
“…Lediglich u È ber die Kristallstruktur von Gd(HSO 4 ) 3 wurde ku È rzlich berichtet [10]. Dieses wurde bei dem Versuch erhalten, Gd 2 (SO 4 ) 3 …”
unclassified
“…At 180 °C, the diffractogram contains only reflections of Y(HSO 4 )(SO 4 ). Indexing was possible using single-crystal data of Er(HSO 4 )(SO 4 ) which where obtained recently . Y(HSO 4 )(SO 4 ) remains stable at 300 °C, but complete decomposition to Y 2 (SO 4 ) 3 is observed at 360 °C.…”
Section: Resultsmentioning
confidence: 99%
“…The reaction of hydrogen sulfates M(HSO 4 ) 3 (M = Ho, Er, Y), which were synthesized following the route given in ref , with water (moisture), was investigated on a θ/θ powder diffractometer (STOE&CIE) equipped with a HDK 2.4 reaction chamber (BÜHLER). Powder samples were placed on a small silver plate in the chamber, which was first purged with dry N 2 .…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation