Die Bildungswärme des Phosphorstickstoffes, P<sub>3</sub>N<sub>5</sub>

Stock, Alfred; Wrede, Franz

doi:10.1002/cber.19070400330

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1938

2017

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“…The equilibrium constant for this reaction was calculated at each temperature for each set of scaled partial pressures. A least-squares adjustment of the values gave the equation log Ki = (-61478 ± 626)/T + (38.364 ± 0.602) (7) (17) E. Steger, Chem. Ber., 94, 266 (1961).…”

Section: Thermodynamic Propertiesmentioning

confidence: 99%

Dissociation energy of PN and other thermodynamic properties for the vaporization of P3N5

Uy¹,

Kohl²,

Carlson³

1968

J. Phys. Chem.

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The data on ZIÍczFíHz/RczFiHi with added Nz at 391°K may well be better represented by a small positive intercept at ~0.05, but it is apparent that a large number of runs would have to be performed (see for instance ref 22) to permit a clear-cut determination as to the existence of an intercept, or not.(32) Similarly, so did plots of ñcia/ñczFsHs and Rtram/RciFtSi, although any difference in behavior of these two functions would certainly not be anticipated.(33) The data in Figure 7 only show the ratio of the products, but the absolute amount of elimination products is, of course, reduced with increasing pressure.

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Section: Thermodynamic Propertiesmentioning

confidence: 99%