2010
DOI: 10.1107/s1600536810017174
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Di-μ1,1-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)]

Abstract: In the centrosymmetric binuclear title complex, [Cu2(C13H19N2O)2(N3)2], the CuII atom adopts an elongated CuON4 square-based pyramidal coordination geometry, arising from the N,N′,O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu⋯Cu separation is 3.2365 (3) Å. A pair of intra­molecular N—H⋯O hydrogen bonds helps to establish the mol­ecular conformation.

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