Developments in the electrochemical synthesis of thia-heterocycles

Swaroop, Toreshettahally R.; Shivaprasad, Chalya Mallappaji; Preetham, Ramesh; Sadashiva, M. P.; Rangappa, Kanchugarakoppal S.

doi:10.1080/10426507.2022.2057498

Cited by 4 publications

(2 citation statements)

References 41 publications

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“…[22] Besides, Hu and co-workers have reported a review on heterogeneous catalysis in electro-synthesis. [23] Recently, we have reported reviews on electrochemical synthesis of sulfur-containing heterocyclic compounds since the beginning of electro-organic synthesis [24] and progresses in the use of transition metal catalysts in electroorganic synthesis from 2000-2021. [25] In continuation of our interest in electro-organic synthesis, [26][27][28] we present a literature review on the synthesis of heterocyclic compounds by electrocatalysis from 2000-2022.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Syntheses of Heterocyclic Compounds Using Transition Metal Catalysts

Swaroop,

Narasimhamurthy,

Umashankara

et al. 2023

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In this review, we present the development of the electrochemical synthesis of heterocyclic compounds catalyzed by transition metal salts and their complexes since 2000. The review is presented as synthesis of nitrogen and oxygen containing heterocycles. The review reflects the applications of transition metal catalysts in the synthesis of aza‐ and oxa‐heterocycles. All reactions are green since they avoid the requirement of chemical oxidants. Electricity as sole oxidant is used to regenerate the active metal catalyst. Thus, in general atom economies of organic electrochemical reactions are high. Nevertheless, use of electrolytes does not affect atom economy. However, one should consider catalytic amount of electrolytes rather than equivalent amount to make electrochemical reactions much green.

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Section: Introductionmentioning

confidence: 99%

Electrochemical Syntheses of Heterocyclic Compounds Using Transition Metal Catalysts

Swaroop,

Narasimhamurthy,

Umashankara

et al. 2023

ChemistrySelect

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“…20 Recently, we have reported a review on electro-organic synthesis of thia-heterocycles. 21 In continuation of our efforts in electro organic synthesis, [22][23][24] we present a review on the use of transition metal catalysts in electro-organic synthesis from 2000 to 2021.…”

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confidence: 99%

Recent Advances in the Use of Transition Metal Catalysts in the Electro-Organic Synthesis

Swaroop¹,

Muddegowda²,

Thakur³

et al. 2022

J. Electrochem. Soc.

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In this review, we present recent advances in the transition metal catalyzed electro-organic transformations since 2000. The review mainly focuses on C-C and C-heteroatom bond-forming reactions along with miscellaneous reactions. Electro-organic synthesis attracts the attention of chemists due to no use of equivalent amount of chemical oxidants. Since electron is a mass free reagent, atom economy of electro-organic reactions is high and hence they are green reactions. We present articles in which transition metal catalysts are regenerated by electricity. Besides, reactions due to sacrificial anodes are also presented.

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Metal Complexes with Redox-Active Ligands in the Indirect Electrosynthesis of Organic Sulfur Compounds

Shinkar’,

Smolyaninov,

Berberova

2023

Russ J Coord Chem

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Developments in the electrochemical synthesis of thia-heterocycles

Cited by 4 publications

References 41 publications

Electrochemical Syntheses of Heterocyclic Compounds Using Transition Metal Catalysts

Electrochemical Syntheses of Heterocyclic Compounds Using Transition Metal Catalysts

Recent Advances in the Use of Transition Metal Catalysts in the Electro-Organic Synthesis

Metal Complexes with Redox-Active Ligands in the Indirect Electrosynthesis of Organic Sulfur Compounds

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