1991
DOI: 10.1021/ie00052a008
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Development of a reaction injection molding encapsulant system. 3. Gel times for the anionic bulk polymerization of styrene with divinylbenzene

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Cited by 3 publications
(4 citation statements)
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“…Karles et al (1991) have found that m P =1.2±0.8 for bulk polymerisation of DVB, different from styrene, which is a source of some complications in kinetic modelling. Notice that no mixed association of anions coming from initiator and from polymer would be allowed using this simplified model (which does not allow either for dependence of m P on the nature of terminal unit).…”
Section: Numerical Treatment Of Non-radical Polymerisation Modelsmentioning
confidence: 99%
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“…Karles et al (1991) have found that m P =1.2±0.8 for bulk polymerisation of DVB, different from styrene, which is a source of some complications in kinetic modelling. Notice that no mixed association of anions coming from initiator and from polymer would be allowed using this simplified model (which does not allow either for dependence of m P on the nature of terminal unit).…”
Section: Numerical Treatment Of Non-radical Polymerisation Modelsmentioning
confidence: 99%
“…After a few fundamental studies on its chemical kinetics (Worsfold, 1970;Eschwey and Burchard, 1975) have been carried out, this system was later found to be useful as a model for RIM encapsulation of electronic parts (Your et al, 1989;Christiansen et al, 1990;Karles et al, 1991).…”
Section: Nomenclature Of Groupsmentioning
confidence: 99%
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“…An example is n-butyllithium initiated bulk polymerisation of styrene in benzene, for which m I = 6 (Worsfold and Bywater, 1960), and m P = 2. Karles et al (1991) have found that m P =1.2±0.8 for bulk polymerisation of DVB, different from styrene, which is a source of some complications in kinetic modelling. Notice that no mixed association of anions coming from initiator and from polymer would be allowed using this simplified model (which does not allow either for dependence of m P on the nature of terminal unit).…”
Section: Numerical Treatment Of Non-radical Polymerisation Modelsmentioning
confidence: 99%