Developing Post-Consumer Recycled Flexible Polypropylene and Fumed Silica-Based Nanocomposites with Improved Processability and Thermal Stability

Abstract

Collection and mechanical recycling of post-consumer flexible polypropylene packaging is limited, principally due to polypropylene being very light-weight. Moreover, service life and thermal–mechanical reprocessing degrade PP and change its thermal and rheological properties according to the structure and provenance of recycled PP. This work determined the effect of incorporating two fumed nanosilica (NS) types on processability improvement of post-consumer recycled flexible polypropylene (PCPP) through ATR-FTIR, TGA, DSC, MFI and rheological analysis. Presence of trace polyethylene in the collected PCPP increased the thermal stability of the PP and was significantly maximized by NS addition. The onset decomposition temperature raised around 15 °C when 4 and 2 wt% of a non-treated and organically modified NS were used, respectively. NS acted as a nucleating agent and increased the crystallinity of the polymer, but the crystallization and melting temperatures were not affected. The processability of the nanocomposites was improved, observed as an increase in viscosity, storage and loss moduli with respect to the control PCPP, which were deteriorated due to chain scission during recycling. The highest recovery in viscosity and reduction in MFI were found for the hydrophilic NS due to a greater impact of hydrogen bond interactions between the silanol groups of this NS and the oxidized groups of the PCPP.

Improvement of Thermal Protection in Recycled Polyolefins through Hybrid Mesoporous Silica–Antioxidant Particles

“…The mechanical recycling of PP involves plastic waste collection, cleaning it to remove impurities, shredding it into small pieces, and melting and reforming it into pellets, and other forms, so it can be employed for manufacturing new products. Proper recycling remains a major challenge because the necessary mechanical processing also promotes the degradation of thermoplastic polymers, resulting in a decrease in their mechanical and thermal properties, as well as a reduction in their subsequent service life [1,2]. This degradation process can be magnified by the presence of free radicals within the polymer chains, developed by their exposure to damaging agents such as heat, humidity, and the sun, among others, during their previous shelf life.…”

Development and Characterization of Polylactic Acid (PLA)-Based Nanocomposites Used for Food Packaging

“…The addition of nanoadditives to polymers in the composition of packaging mixtures improves their mechanical, optical, thermal, and barrier properties; subsequently, their use in the circular economy is more viable [12]. Moreover, the introduction of a quantity of 1-4% of fumed nanosilica led to a high thermal stability of the nanocomposites, presenting an improved processability [13]. In addition, silica nanoparticles (SiO 2 ) can provide all these physico-mechanical properties [14], as well as antibacterial and antioxidant properties, to packaging materials [15,16].…”