Deuterium isotope effects in the radiation chemistry of glassy and polycrystalline hydrocarbons

Wilkey, D. D.; Fenrick, Harold W.; Hager, S. L.; Bremer, Noel J.; Willard, John E.

doi:10.1063/1.434052

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1977

1988

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Cited by 13 publications

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“…Phys., 73, 1540 (1980), n-decane containing electron scavengers after 7 radiolysis at 77 K,2 despite the presence of ef in the same alkanes, following 7 radiolysis of polycrystalline samples. 16,17 The cations of these alkanes were observed in 3MP glasses containing the alkane as a solute.2…”

Section: Discussionmentioning

confidence: 99%

Positive ions in alkane and mixed alkane glasses

Teather¹,

Klassen²

1981

J. Phys. Chem.

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Section: Discussionmentioning

confidence: 99%

Positive ions in alkane and mixed alkane glasses

Teather¹,

Klassen²

1981

J. Phys. Chem.

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A Radical Post‐Scavenging Study of Irradiated Cyclic Hydrocarbons in the Solid State

Tilquin

Allaert

Claes

1977

Bulletin des Soc Chimique

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Cycloalkanes were irradiated in the solid phase at 77 K. Post‐irradiation scavenging of radicals by dissolving the irradiated cycloalkane at low temperature (100 ‐ 165 K) in a propane‐oxygen mixture lowers the dicycloalkyl and cycloalkene G values to an extent of 35‐55%. From the Δ G decrease values, we propose that the trapped radical G values be 3.1, 2.7 and 2.7 at 77 K for cyclopentyl, cyclohexyl and cycloheptyl radicals, respectively.

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