Abstract:Recently the Ministry of Environment in Korea has developed the total maximum daily load program in accordance with the target pollutant and its concentration goal on four major large rivers. Since the program is largely related to regional development, nonpoint source control is both important and topical. Of the various nonpoint sources, highways are stormwater intensive land uses since they are impervious and have high pollutant mass emissions from vehicular activity. The event mean concentration (EMC) is u… Show more
“…The exit gas flowed through two ORBO activated carbon tubes (20/40 large charcoal, Sigma Aldrich) in series to capture any volatized naphthalene. From the activated carbon traps, the air was bubbled through two carbon dioxide traps (each contained 15 mL of 2 M NaOH) in series using fine bubble diffusers (Supelco) to capture any 14 CO 2 produced via naphthalene mineralization. An activated carbon tube was also affixed to the air input port to prevent any possible contamination from the ambient air in the room; this carbon tube was removed when adding water to the columns.…”
Section: ■ Materials and Methodsmentioning
confidence: 99%
“…Sampling and analysis were conducted in an effort to account for all of the 14 C-naphthalene added to the system. Excess water leached through the column was collected from the leachate reservoir (Figure 1), weighed, and a subsample was analyzed for 14 C content. The activated carbon traps were sacrificed weekly, hexane-extracted, and the extracts were analyzed for 14 C content.…”
Bioretention cells are increasingly popular in low-impact development as a means to sustainably mitigate the environmental problems associated with stormwater runoff. Yet, much remains to be known regarding the removal and ultimate fate of pollutants such as petroleum hydrocarbons in bioretention cells. In this work, laboratory-scale bioretention cells were constructed inside sealed glass columns. The columns were periodically spiked with (14)C-naphthalene over a 5-month period and the fate of this representative hydrocarbon and the influence of vegetation on naphthalene fate was studied. Three column setups were used: one planted with a legume (Purple Prairie Clover, Dalea purpureum), one planted with grass (Blue-Joint Grass, Calamagrostis canadensis), and one unplanted (i.e., control). Overall naphthalene removal efficiency was 93% for the planted columns and 78% for the control column. Adsorption to soil was the dominant naphthalene removal mechanism (56-73% of added naphthalene), although mineralization (12-18%) and plant uptake (2-23%) were also important. Volatilization was negligible (<0.04%). Significant enrichment of naphthalene-degrading bacteria occurred due to contaminant exposure and plant growth as evidenced by increased biodegradation activity and increased naphthalene dioxygenase gene concentrations in the bioretention media. This research suggests that bioretention is a viable solution for sustainable petroleum hydrocarbon removal from stormwater, and that vegetation can enhance overall performance and stimulate biodegradation.
“…The exit gas flowed through two ORBO activated carbon tubes (20/40 large charcoal, Sigma Aldrich) in series to capture any volatized naphthalene. From the activated carbon traps, the air was bubbled through two carbon dioxide traps (each contained 15 mL of 2 M NaOH) in series using fine bubble diffusers (Supelco) to capture any 14 CO 2 produced via naphthalene mineralization. An activated carbon tube was also affixed to the air input port to prevent any possible contamination from the ambient air in the room; this carbon tube was removed when adding water to the columns.…”
Section: ■ Materials and Methodsmentioning
confidence: 99%
“…Sampling and analysis were conducted in an effort to account for all of the 14 C-naphthalene added to the system. Excess water leached through the column was collected from the leachate reservoir (Figure 1), weighed, and a subsample was analyzed for 14 C content. The activated carbon traps were sacrificed weekly, hexane-extracted, and the extracts were analyzed for 14 C content.…”
Bioretention cells are increasingly popular in low-impact development as a means to sustainably mitigate the environmental problems associated with stormwater runoff. Yet, much remains to be known regarding the removal and ultimate fate of pollutants such as petroleum hydrocarbons in bioretention cells. In this work, laboratory-scale bioretention cells were constructed inside sealed glass columns. The columns were periodically spiked with (14)C-naphthalene over a 5-month period and the fate of this representative hydrocarbon and the influence of vegetation on naphthalene fate was studied. Three column setups were used: one planted with a legume (Purple Prairie Clover, Dalea purpureum), one planted with grass (Blue-Joint Grass, Calamagrostis canadensis), and one unplanted (i.e., control). Overall naphthalene removal efficiency was 93% for the planted columns and 78% for the control column. Adsorption to soil was the dominant naphthalene removal mechanism (56-73% of added naphthalene), although mineralization (12-18%) and plant uptake (2-23%) were also important. Volatilization was negligible (<0.04%). Significant enrichment of naphthalene-degrading bacteria occurred due to contaminant exposure and plant growth as evidenced by increased biodegradation activity and increased naphthalene dioxygenase gene concentrations in the bioretention media. This research suggests that bioretention is a viable solution for sustainable petroleum hydrocarbon removal from stormwater, and that vegetation can enhance overall performance and stimulate biodegradation.
“…Generally, urban stormwater runoff contains 120.1-422.1 µg/L, 94.9-403.7 µg/L and 11.1-32.0 µg/L Cu, Zn and Pb, respectively. The main heavy metals contained in the general urban stormwater runoff are Cu, Pb and Zn [26]. In the biowaste filter media, the removal efficiency of Pb and Zn was about 40%-60%.…”
Section: Evaluation Of Water Balance and Pollutant Removal Efficiencymentioning
In this study, biowaste such as walnut shells (WS), cockle shells (CS), and gingko shells (GS) was evaluated for applicability as soil filter media in low impact development (LID) techniques. Biowastes used in the experiment showed lightweight , high porosity, and high permeability characteristics compared with sand or gravel which are conventionally used in LID. Especially, CS and WS showed high non-point pollutant removal efficiency due to protrusion of filter media surface and macro-and micro-porous. CS were found to be suitable for the infiltration capacity, as it showed high filtration and pollutant reduction. WS exhibited high heavy metal removal performance but was found to have possibility of organic matter leaching. GS were evaluated to be adaptable to green roof as filter media with lightweight and constant filtration capability. The findings of this research are useful for the application of biowaste as filter media in LID techniques.
“…Continuous flow measurements were performed and rainfall data collected to obtain a relatively unbiased approximation of the pollutant mass loads. The total sampling time was adjusted to approximate the time during which the "first flush" was processed [10]. Generally, at least 12 samples were manually collected at both the inlet and outlet.…”
This study attempted to develop and suggest a more appropriate method for the determination of event mean concentration (EMC) and pollutant removal efficiency of a stormwater best management practice (BMP) considering rainfall. The stormwater runoff and hydrologic data gathered from 22 storm events during a 28-month monitoring period on a swirl and filtration type of BMP were used to evaluate the developed methods. Based on the findings, the modified EMC method resulted in lower (average) values than the overall EMC, although the differences were not significant (P>0.05). By comparison, the developed 'Rainfall Occurrence Ratio' (ROR) method was most significantly correlated (r=0.967 to 988, P<0.009) with the other existing removal efficiency determination methods such as the 'Efficiency Ratio' (ER), 'Summation of Loads' (SOL) and 'Regression of Loads' (ROL) methods. In addition, the ROR method gave the highest efficiency values, with no significant differences with any of the pollutant parameters, unlike the other three methods. These results were obtained because the ROR method integrated both pollutant loading and rainfall, which are not considered by the other three methods. Therefore, this study proved the suitability of the modified EMC and ROR methods for application in other BMP monitoring studies.
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