2010
DOI: 10.1590/s0100-40422010000700020
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Determinação seletiva de tributilestanho na presença de Sn(IV) em amostras ambientais usando HG-ICP OES e Saccharomyces cerevisiae como material sorvente

Abstract: Recebido em 9/11/09; aceito em 15/3/10; publicado na web em 20/7/10 SELECTIVE DETERMINATION OF TRIBUTYLTIN IN THE PRESENCE OF Sn(IV) IN ENVIRONMENTAL SAMPLES USING HG-ICP OES AND Saccharomyces cerevisiae AS SORBING MATERIAL. A method for selective determination of tributyltin in the presence of Sn(IV) by combining hydride generation inductively coupled plasma optical emission spectrometry (HG-ICP OES) and solid phase extraction (SPE) using baker's yeast is proposed. The procedure is based on selective retentio… Show more

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Cited by 5 publications
(7 citation statements)
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“…A rapid method (7 minute GC separation) for the determination of OTCs combined SPME with GC-ICP-MS. 135 A baker's yeast has been proposed as a suitable solid phase extractant. 136 Multi-element methods are always welcome as the effort required to carry out speciation analysis is still considerable. A method for the determination of Br and I species in drinking water by IC-ICP-MS 137 used an ICS-A23 column to separate the species present with a mobile phase of 0.03 M ammonium carbonate.…”
Section: Speciationmentioning
confidence: 99%
“…A rapid method (7 minute GC separation) for the determination of OTCs combined SPME with GC-ICP-MS. 135 A baker's yeast has been proposed as a suitable solid phase extractant. 136 Multi-element methods are always welcome as the effort required to carry out speciation analysis is still considerable. A method for the determination of Br and I species in drinking water by IC-ICP-MS 137 used an ICS-A23 column to separate the species present with a mobile phase of 0.03 M ammonium carbonate.…”
Section: Speciationmentioning
confidence: 99%
“…262 The procedure is based on selective retention of TBT by the yeast at pH 6. A detection limit of 1.9 mg L À1 and a quantification limit of 6.3 mg L À1 were obtained.…”
Section: Tinmentioning
confidence: 99%
“…The accuracy of the method was validated against fortified water TMDA 61 (NWRI) and Dogfish Liver DOLT-3 (NRCC) CRMs. Silva et al 36 employed HG-ICP-OES and SPE (with a baker's yeast solid phase) for the selective determination of tributyltin in the presence of Sn IV in river water, seawater, and biological abstracts. Unal and Yalcin 163 developed a continuous-flow HG laserinduced breakdown spectroscopy system for the determination of Sn in aqueous samples.…”
Section: Cadmium Feng and Liumentioning
confidence: 99%
“…Silva and Brazilian co-workers 36 selectively determined tributyltin in the presence of Sn IV in environmental samples using HG-ICP-OES and saccharomyces cerevisiae (Baker's yeast) as sorbing material. The procedure was based on the retention of TBT by the yeast at pH 6.…”
mentioning
confidence: 99%